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Author : Wenbo Ma
Publisher :
Page : pages
File Size : 33,92 MB
Release : 2015
Category :
ISBN :
Author : Xiao-Feng Wu
Publisher : John Wiley & Sons
Page : 596 pages
File Size : 18,50 MB
Release : 2016-03-07
Category : Technology & Engineering
ISBN : 3527338888
Reflecting the tremendous growth of this hot topic in recent years, this book covers C-H activation with a focus on heterocycle synthesis. As such, the text provides general mechanistic aspects and gives a comprehensive overview of catalytic reactions in the presence of palladium, rhodium, ruthenium, copper, iron, cobalt, and iridium. The chapters are organized according to the transition metal used and sub-divided by type of heterocycle formed to enable quick access to the synthetic route needed. Chapters on carbonylative synthesis of heterocycles and the application of C-H activation methodology to the synthesis of natural products are also included. Written by an outstanding team of authors, this is a valuable reference for researchers in academia and industry working in the field of organic synthesis, catalysis, natural product synthesis, pharmaceutical chemistry, and crop protection.
Author : Daniel Sole
Publisher : Academic Press
Page : 368 pages
File Size : 28,89 MB
Release : 2018-05-17
Category : Science
ISBN : 0128116528
Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metals to produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (mainly aza- and oxa-heterocycles). As such, it covers recent applications on the synthesis of heterocycles, also describing the details of the novel transformations in a didactic manner to motivate readers in search of new catalytic processes. The editors have included state-of-the-art strategies, including transition-metal reactions involving unsaturated systems (reactions of allenes, new gold(I)-catalyzed reactions, and Prins reaction). Chapters highlight the versatility of organopalladium chemistry dealing with carbonylative transformations, C-H activation reactions, coupling processes, and the control of the ambiphilic character of organopalladium species. Finally, the book discusses new reactions leading to heterocycles based on C-H activation processes catalyzed by other metals (Rh, Ru, Co). Written by an outstanding team of authors who are leading experts in organometallic chemistry and organic synthesis, this book is a valuable resource not only for chemists mainly focused on synthesis, but also for those interested in reaction mechanisms involving transition metals. Helpfully organized by transformation type to stimulate the search for new synthetic processes Completely illustrated and written by global experts Includes thoughtfully selected strategies chosen by the editors to exemplify the state-of-the-art of the subject, including transition-metal reactions involving unsaturated systems, organopalladium chemistry, and metal-catalyzed C-H activation
Author : Debabrata Maiti
Publisher : Springer
Page : 0 pages
File Size : 26,5 MB
Release : 2024-09-27
Category : Science
ISBN : 9783031708428
In this book, recent advancements in the heterocycles functionalization by using different transition metals have been described. Heterocycles are the central point mainly in drug discovery and various other fields. The ease with which one can functionalize these scaffolds mainly accounts for the whole process output. In the last three decades, C-H activation has emerged as the sustainable and economic way to functionalize the heterocycles. Numerous catalytic methods have been developed and are being developed by applying mainly transition metals. The books main emphasis has been given to mechanistic aspects and the application of developed methodologies for the functionalization of natural scaffolds. The book is useful for researchers who are working in the area of C-H activation/functionalization in academia and industry.
Author : András Kotschy
Publisher : Springer Science & Business Media
Page : 224 pages
File Size : 11,72 MB
Release : 2005-09-30
Category : Science
ISBN : 9781402036248
"Heterocycles from Transition Metal Catalysis: Formation and Functionalization" provides a concise summary of the prominent role of late transition metal (palladium, nickel, copper) catalysed processes in the synthesis and functionalization of heterocyclic systems. It gives an introduction to catalytic transformations, an overview of the most important reaction types, and presents synthetically useful catalytic processes classified by the target system and the type of transformation. The book provides a representative selection of transition metal catalysed reactions transformations that are relevant in heterocyclic chemistry. In this way, the authors present a useful resource for members of the academic community looking for a textbook as well as industrial chemists in search of a reference book. This book will be an invaluable resource for synthetic chemists, medicinal chemists, and those more generally interested in applied catalysis.
Author : Xiao-Feng Wu
Publisher : Royal Society of Chemistry
Page : 315 pages
File Size : 29,98 MB
Release : 2015
Category : Science
ISBN : 1782621369
An introduction to transition metal catalyzed coupling reactions of double-functionalized arenes in heterocycle synthesis.
Author : Xiao-Feng Wu
Publisher : Springer
Page : 176 pages
File Size : 33,14 MB
Release : 2015-12-14
Category : Science
ISBN : 3319249630
The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field. All chapters from Topics in Heterocyclic Chemistry are published Online First with an individual DOI. In references, Topics in Heterocyclic Chemistry is abbreviated as Top Heterocycl Chem and cited as a journal.
Author : Jianbo Wang
Publisher : John Wiley & Sons
Page : 450 pages
File Size : 18,40 MB
Release : 2022-05-16
Category : Science
ISBN : 3527347992
Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer. Highlights the dynamic nature of the field of transition-metal-catalyzed carbene transformations Summarizes the catalytic radical approach for selective carbene cyclopropanation, high enantioselectivity in X-H insertions, and bio-inspired carbene transformations Introduces chiral N,N'-dioxide and chiral guanidine-based catalysts and different transformations with gold catalysis Discusses approaches in cycloaddition reactions with metal carbenes and polymerization with carbene transformations Outlines multicomponent reactions through gem-difunctionalization and transition-metal-catalyzed cross-coupling using carbene precursors Transition Metal-Catalyzed Carbene Transformations is essential reading for all chemists involved in organometallics, including organic and inorganic chemists, catalytic chemists, and chemists working in industry.
Author : Xiao-Feng Wu
Publisher : Royal Society of Chemistry
Page : 335 pages
File Size : 19,84 MB
Release : 2014-05-21
Category : Science
ISBN : 1849739358
Heterocycle synthesis is one of the largest areas of modern organic chemistry. Heterocycles have a broad range of applications including pharmaceuticals, agrochemicals and dyes, and are the core structure to around 90% of naturally-occurring molecules. Transition metal catalysts have become favoured in heterocycle synthesis, not least because of their low cost, but also due to their relatively low environmental toxicity and biocompatibility. This book presents an overview of the state-of-the-art in transition metal catalysis for heterocycle synthesis. Each metal is discussed in turn, presenting a comprehensive source of information on the use of zinc, iron, copper, cobalt, manganese, and nickel in a sustainable and economic manner. Referencing the latest primary literature, and authored by active researchers in the field, this book is a must-have resource for anyone wishing to undertake an economic and sustainable approach to heterocycle synthesis.
Author : Frank Glorius
Publisher : Springer
Page : 240 pages
File Size : 27,77 MB
Release : 2007-02-05
Category : Science
ISBN : 3540369309
In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.