[PDF] Synthesis Of Fluoro Organic Compounds eBook

Author : Peer Kirsch
Publisher : John Wiley & Sons
Page : 320 pages
File Size : 36,81 MB
Release : 2006-03-06
Category : Science
ISBN : 3527604197

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In this handbook, Peer Kirsch clearly shows that this exciting field is no longer an exotic area of research. Aimed primarily at synthetic chemists wanting to gain a deeper understanding of the fascinating implications of including the highly unusual element fluorine in organic compounds, the main part of the book presents a wide range of synthetic methodologies and the experimental procedures selected undeniably show that this can be done with standard laboratory equipment. To round off, the author looks at fluorous chemistry and the applications of organofluorine compounds in liquid crystals, polymers and more besides. This long-awaited book represents an indispensable source of high quality information for everyone working in the field.

Author : Richard D. Chambers
Publisher : CRC Press
Page : 426 pages
File Size : 42,84 MB
Release : 2004
Category : Science
ISBN : 9780849317903

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The introduction of carbon-fluorine bonds into organic compounds can profoundly influence their chemical and physical properties when compared to their non-fluorine-containing analogues, leading to a range of man-made materials with highly desirable properties. These molecules are of interest across the wide spectrum of industrial and academic organic chemistry, from pharmaceuticals, through fine and specialty chemicals to polymers. From Prozac to Teflon, many of the most important products of the chemical and life-science industries rely on organic fluorine chemistry for their useful properties. This book covers both the preparative methodologies and chemical properties of partially and highly fluorinated organic systems.

Author : V. A. Soloshonok
Publisher : John Wiley & Sons
Page : 704 pages
File Size : 42,98 MB
Release : 1999-07-09
Category : Science
ISBN :

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Written by a leading expert in the field, this is a comprehensivereview of the methods for preparing stereochemically definedfluorine-containing compounds of biomedical importance. Fluorinated organic compounds are well known for their unusualreactivity but the growing importance of these compounds in thebiomedical field has been accompanied by an increasing awareness ofthe necessity to synthesise and explore the biological propertiesof stereochemically defined fluoro-compounds. This is the firstbook written on this exciting area of research. It contains: * detailed reviews on stereocontrolled synthesis of biologicallyimportant compounds * 21 chapters covering the main areas of asymmetric synthesis andbiocatalysts where fluorine plays a key role * mechanisms and methods for synthesizing fluoro-organiccompounds Written for professionals involved in organic, physical andorganofluorine chemistry, natural product synthesis, biological,pharmaceutical and other life science related industries.

Author : I.L. Knunyants
Publisher : Springer Science & Business Media
Page : 307 pages
File Size : 41,81 MB
Release : 2012-12-06
Category : Science
ISBN : 3642702074

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Recently there has been a tremendous growth in the chemistry of fluoroorganic compounds, which find wide applicatiori in various fields of technique and are used to solve some basic theoretical problems. The chemical properties of these compounds are rather specific, as well as the methods for their preparation. We realized that no good handbooks on the preparation offluoro organic compounds were available, whereas the methods of pre paration are scattered in numerous scientific papers and patents. Even such a well-known publication as Organic Syntheses contains just a few methods of preparation of fluoroorganic compounds. As a consequence, not only for newcomers but even for specialists, searching for simple and convenient methods for the preparation of the required compounds is tedious. To alleviate the problem, we undertook to prepare this book, which presents detailed preparation methods of more than 300 flu oro organic compounds. Emphasis has been laid on syntheses of polyfluorinated compounds, since they are of major interest with respect to preparation and utility. Preparation of fluoroorganic compounds is based both on the classical methods of organic chemistry and on the specific ones, which is due to the difficulty or even impossibility of the direct introduction of fluorine into a definite position of organic mole cule. Most organic compounds of fluorine are prepared by a suc cession of conversions of a relatively small number of starting compounds.

Author : Milos Hudlicky
Publisher : Springer Science & Business Media
Page : 208 pages
File Size : 18,63 MB
Release : 2012-12-06
Category : Science
ISBN : 1461586429

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The present book is essentially based on the lectures on the chemistry of organic compounds of fluorine that I gave in 1969 at Virginia Polytechnic Institute in Blacksburg, Virginia, as a graduate course. References to material published to the end of 1969 are included. The book is primarily meant to provide the background for such a course, and, at the same time, to be a brief survey of recent knowledge in, and an introduction to deeper study of, this area of chemistry, which has been treated in a number of com prehensive monographs. I would like to thank Professor S. C. Cohen, Syracuse University, for the compilation of the data on mass spectra and nuclear magnetic res onance spectra, and my son, Tomas Hudlicky, and my daughter, Eva Hudlickci, for their help with the indexes. MILOS HUDLICKY February 13, 1970 Virginia Polytechnic Institute and State University Blacksburg, Virginia vii Contents CHAPTER 1. Introduction ......................................................... 1 Development of Fluorine Chemistry ......................................... .

Author : Henri Groult
Publisher : Elsevier
Page : 792 pages
File Size : 47,85 MB
Release : 2016-11-04
Category : Science
ISBN : 0128037903

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Modern Synthesis Processes and Reactivity of Fluorinated Compounds focuses on the exceptional character of fluorine and fluorinated compounds. This comprehensive work explores examples taken from all classes of fluorine chemistry and illustrates the extreme reactivity of fluorinating media and the peculiar synthesis routes to fluorinated materials. The book provides advanced and updated information on the latest synthesis routes to fluorocompounds and the involved reaction mechanisms. Special attention is given to the unique reactivity of fluorine and fluorinated media, along with the correlation of those properties to valuable applications of fluorinated compounds. Contains quality content edited, and contributed, by leading scholars in the field Presents applied guidance on the preparation of original fluorinated compounds, potentially transferable from the lab scale to industrial applications Provides practical synthesis information for a wide audience interested in fluorine compounds in many branches of chemistry, materials science, and physics

Author : L.A. Alekseeva
Publisher : Springer
Page : 306 pages
File Size : 12,65 MB
Release : 1989-11-02
Category : Science
ISBN :

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The book summarizes and gives a critical analysis of the literature on the use of reactive covalent fluorides (organic and inorganic) for the synthesis of fluoroorganic compounds. New methods of using SF4 for the fluorination of complex polyfunctional organic compounds are described. The prospects are shown for the selective fluorinations of complex compounds with non-traditional fluorinating agents (halogen fluorides, XeF2, fluorosulphuranes, N-F- and O-F-containing compounds). The book gives recommendations for the practical use of these fluorides, and typical synthetic procedures. It introduces the beginner to modern methods of fluorination and helps qualified scientists and technologists to choose the optimal methods of synthesis. Using the fluorinating agents described in this book, it is possible to synthesize various fluorine-containing substances.

Author : Viacheslav A. Petrov
Publisher : John Wiley & Sons
Page : 535 pages
File Size : 24,76 MB
Release : 2009-09-22
Category : Science
ISBN : 047052894X

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A thorough survey of synthetic methods, chemistry, and applications of major classes of fluorinated heterocycles Merging organic, heterocyclic, and fluoroorganic chemistry, fluorinated heterocyclic compounds have distinctively desirable properties suitable for use in pharmaceuticals and agrichemicals, especially their ability to penetrate the cell membrane barrier for drug absorption. Offering a needed overview of this relatively new addition to the heterocyclic family, this essential reference provides the latest state-of-the-art information on key application areas within fluorine chemistry. With contributions from experts from both industry and academia, the book covers the chemistry, synthesis, and applications of fluorinated heterocycles with chapters on: Three-, four-, five-, six-, and seven-membered fluorine-containing heterocycles Fluorinated nucleosides Fluorointermediates Applications of fluorinated heterocycles in agricultural products Pharmaceuticals containing fluorinated heterocycles Technical applications of fluorinated heterocycles Written by a team of world-recognized experts in the area of organic and industrial chemistry of fluorine, Fluorinated Heterocyclic Compounds: Synthesis, Chemistry, and Applications will prove valuable to both students and researchers from academia and industry seeking further knowledge of the synthetic methods, chemistry, and applications of major classes of fluorinated heterocycles.

Author : Axel Haupt
Publisher : Walter de Gruyter GmbH & Co KG
Page : 846 pages
File Size : 50,42 MB
Release : 2021-03-22
Category : Science
ISBN : 3110659506

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Organic and Inorganic Fluorine Chemistry provides an introduction to fluorine chemistry and an overview of the most important fluorinated compounds and general preparation techniques. The book is divided into three parts, covering general aspects, inorganic fluorides and fluoroorganic compounds. The inorganic part presents the most important element fluorides and oxyfluorides, their preparation as well as their most characteristic properties. The organic section focuses on the different types of fluorination and the corresponding reagents. The application of these techniques is discussed for many different types of substrates. The book addresses advanced students in chemistry as well as researchers in academia and industry. The readers will benefit from a large number of original references which give access to further information. In addition, study questions at the end of each chapter will help to repeat and internalise the most important aspects.