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Raman Spectroscopy of Gases and Liquids

Author : A. Weber
Publisher : Springer Science & Business Media
Page : 327 pages
File Size : 44,99 MB
Release : 2012-12-06
Category : Science
ISBN : 3642812791

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The Raman effect is a most useful tool for the study of molecular vibrations and molecular structure. Information about the structure and symmetry of molecules, as well as about their vibrational energies can be obtained to a reasonable degree of satisfaction from their infrared and Raman vibrational spectra. The body of knowl edqe of the vibrational infrared and Raman spectra of molecules is immense and is now so well organized and understood that it is found to be represented in any stan dard upper level undergraduate curriculum in chemistry. The rotational energies of a molecule and quantitative details about its structure can only be obtained through the techniques of microwave, and high-resolution infrared and Raman spectroscopy of low pressure gases and vapors. The results of such investigations are of interest . not only to the academic scientists, but also to scientists and engineers who are active in applied fields of chemistry and physics, as well as the atmospheric sciences. This book deals with basic investigations of the Raman scattering of light by gases, with some attention also being given to liquid substances. After a brief in troductory chapter that delineates the historical development of Raman spectroscopy of gases, high-resolution rotation-vibrational and pure rotational Raman spectros copy is described in Chapters 2 and 3. The all-important intensity parameter, the Raman scattering cross section, is treated in Chapter 4, while the broadening of Raman lines due to the effects of intermolecular forces is taken up in Chapter 5.

Spectroscopy of Molecular Rotation in Gases and Liquids

Author : A. I. Burshtein
Publisher : Cambridge University Press
Page : 310 pages
File Size : 25,21 MB
Release : 1994-07-21
Category : Science
ISBN : 0521454654

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A review of the fundamental concepts and models which underpin the spectroscopic study of gases and liquids, first published in 1994.

Handbook of Raman Spectroscopy

Author : Ian R. Lewis
Publisher : CRC Press
Page : 1076 pages
File Size : 28,84 MB
Release : 2001-08-08
Category : Science
ISBN : 9781420029253

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This work covers principles of Raman theory, analysis, instrumentation, and measurement, specifying up-to-the-minute benefits of Raman spectroscopy in a variety of industrial and academic fields, and how to cultivate growth in new disciplines. It contains case studies that illustrate current techniques in data extraction and analysis, as well as over 500 drawings and photographs that clarify and reinforce critical text material. The authors discuss Raman spectra of gases; Raman spectroscopy applied to crystals, applications to gemology, in vivo Raman spectroscopy, applications in forensic science, and collectivity of vibrational modes, among many other topics.

Raman Spectroscopy Under Liquid Nitrogen (RUN)

Author : Robert N. Compton
Publisher : Springer Nature
Page : 122 pages
File Size : 25,70 MB
Release : 2022-06-14
Category : Science
ISBN : 3030993957

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This book describes a simple yet innovative method for performing Raman spectroscopy of samples submerged under liquid nitrogen. While Raman spectroscopy has proven to be a powerful tool for the characterization of the structure of matter in the gaseous, liquid, and solid phases, one major difficulty in its application has been laser damage to the material under investigation, especially for biological samples. This book demonstrates how immersion of the sample in liquid nitrogen protects the sample from thermal degradation and oxidation at high incident laser power and allows improvements in sensitivity and spectral resolution over room-temperature Raman spectroscopy, leading to the so-called RUN (Raman Spectroscopy Under liquid Nitrogen) technique. Cooling to liquid nitrogen temperature also allows the selection of the lowest energy molecular conformation for molecules which may have many low energy conformers. In addition, the presence of liquid nitrogen over a roughened surface improves the sensitivity of Surface Enhanced Raman Spectroscopy (SERS), enabling the closely related SERSUN (Surface-Enhanced Raman Spectroscopy Under liquid Nitrogen) technique. This book starts with the theoretical and experimental basics of Raman and polarized Raman spectroscopy, before moving on to detailed descriptions of RUN and SERSUN. Room temperature and RUN spectra are provided for over fifty molecules.

Laser Raman Gas Diagnostics

Author : Marshall Lapp
Publisher : Springer Science & Business Media
Page : 387 pages
File Size : 12,17 MB
Release : 2013-03-14
Category : Science
ISBN : 1468421034

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The Laser Raman Workshop on the r"eas urement of Gas Properti es i sone of aseries of occasional meetings organized in an informal workshop format through the stimulation of Project SQUID, Office of Naval Research. This workshop is the second to be organized on gas-phase applications of Raman scattering. Both Raman workshops were supported by Project SQUID, ONR, and the Air Force Aero Propulsion Laboratory, Wright-Patterson Air Force Base. The first Raman Workshop was held at the AVCO Everett Research Laboratory, Everett, Massachusetts, with their co-sponsorship in January 1972 under the chairmanship of D. A. Leonard. The present meeting was co-sponsored by the General Electric Research and Development Center, and held at their facility in Schenectady, New York. We are grateful to Project SQUID, AFAPL, and GE for their generous financial support of this Workshop, and to Project SQUID for underwriting the publication costs of the Proceedings. As is always the case for successful meetings, many people contributed substantially to the organization and execution of this workshop. Professor Robert Goulard supported, aided, and encouraged us in the most helpful ways, and we are indebted to him. We received further valuable support and assistance from Dr. Ralph Roberts, Director, and Mr. James R. Patton, Jr., of the Power Branch, Office of Naval Research; from Dr. William H. Heiser, Chief Scientist of the Aero Propulsion Laboratory; and from Dr. James M.

Non-Linear Raman Spectroscopy and Its Chemical Aplications

Author : W. Kiefer
Publisher : Springer Science & Business Media
Page : 623 pages
File Size : 32,36 MB
Release : 2012-12-06
Category : Science
ISBN : 9400979126

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In recent years a number of non-linear Raman spectroscopic techniques have been substantially developed and are now proving to be powerful methods for the solution of many problems not only in spectroscopy but also in chemistry, physics and biology. These techniques include hyper Rayleigh and hyper Raman spectroscopy, coherent anti-Stokes Raman Spectroscopy (CARS), Raman Gain and In verse Raman Spectroscopy, Photoacoustic Raman Spectroscopy (PARS) and the Raman Induced Kerr Effect (RIKE). Hyper Raman spectro scopy although experimentally difficult is valuable for investi gating transitions which are not active in the infrared or in the linear Raman effect; and the other non-linear Raman effects can provide signal strength and resolution which are orders of magni tude higher than those obtainable with linear Raman spectroscopy. The thirty chapters in this book will form the basis of lectures presented at the NATO Advanced Study Institute in Bad Windsheim, F. R. Germany from August 23 - September 3, 1982.

Infrared and Raman Spectroscopy

Author : Bernhard Schrader
Publisher : John Wiley & Sons
Page : 807 pages
File Size : 18,82 MB
Release : 2008-09-26
Category : Science
ISBN : 3527615423

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This book is an excellent introduction to vibrational spectroscopy for scientists in academia and industry. Both infrared and Raman spectroscopy are covered comprehensively and up-to-date. Therefore the book may also be used as a handbook for easy reference. Written in the language of chemists, it explains the basic theory and instrumentation, the interpretation and evaluation of spectra. Furthermore numerous, worked-out examples of practical applications are presented. Therefore the reader is enabled to apply infrared and Raman spectroscopy for solving his own problem and to design suitable experimental procedures. This book also serves as a guide to the relevant literature