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Molecular Basis of Polymer Networks

Author : Artur Baumgärtner
Publisher : Springer
Page : 248 pages
File Size : 14,23 MB
Release : 1989-11-16
Category : Science
ISBN :

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The workshop on the "Molecular Basis of Polymer Networks", held October 5- 7, 1988 in 1iilich, FRG, continued a series of workshops jointly organized by the Institute Laue Langevin (ILL) in Grenoble, and the Institute of Solid State Physics of the KFA, 1iilich. The aim of this workshop was to provide a platform for discussions between theoreticians and experimentalists interested in the physics of polymer networks, in the hope that the two types of discussion would be synergistic. As revealed by the title of this workshop, the main focus of the lectures was on molecular aspects of the problem. The individual parts of these proceedings cover various approaches. Following quite general comments from a physicist examining the situation from "outside", various new theoretical concepts are developed. During the last decade the advent of Small Angle Neutron Scattering (SANS) has allowed the molecular structure of polymer networks to be studied and thus the reliability of the theories to be tested directly at the molecular level. Recent advances in this field are presented. The use of new techniques such as 2H NMR or QELS and the refinements of more classical, mechanical experimental measure ments have provided new information about the relation between the macroscopic behavior and the microscopic structure of polymer networks. Some recent results in this area are discussed for both chemically cross-linked networks and gels built by specific interchain interactions.

Polymer Motion in Dense Systems

Author : Dieter Richter
Publisher : Springer
Page : 0 pages
File Size : 49,94 MB
Release : 1988
Category : Science
ISBN : 9783642933806

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The nine review articles and roughly 30 contributed papers contained in this volume survey the present understanding of the molecular motion of polymers in concentrated solutions, melts and the amorphous state. Although the main emphasis is on results from neutron scattering experiments, about half of the contributions relate to complementary techniques such as light scattering and NMR. The book highlights three areas of active reseach that have received increasing attention in recent years. First, work on polymer relaxation near the glass transition and in glassy systems has shown that the application of different experimental techniques is indispensable due to the broad range of time scales over which these phenomena occur on a molecular level. Second, it is reported that the internal Brownian motion of long chain molecules and their diffusion in an entangled environment still does not have a generally accepted physical picture, although detailed insights into the microscopic motion have been obtained. Third, important progress has been made in unravelling the characteristics of phase separation of polymer blends, in which modifications to the ordinary laws of diffusion are of particular interest.

Neutron, X-ray and Light Scattering

Author : Peter Lindner
Publisher : North Holland
Page : 396 pages
File Size : 21,85 MB
Release : 1991
Category : Science
ISBN :

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This book is devoted to a simple practical approach to neutron, X-ray and light scattering experiments, involving model calculation of the scattering and mathematical transformation. It is intended to attract colloid and polymer scientists using scattering methods in their laboratory or at common research facilities. The primary objective is to explain the current methodology of elastic and quasi-elastic scattering techniques (avoiding both under and over-exploitation of data) rather than a general course on colloids and polymers. Basic information on data interpretation, on the complementarity of the different types of radiation, as well as information on recent applications and developments are presented.