[PDF] Photorefractive Polymers For Integrated Optics eBook
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The goal of this project was to produce and characterize improved organic ferroelectric materials with emphasis on improving the response time and sensitivity. We demonstrated 300-fold improvements in the mobility of photorefractive polymer composites by identifying and mitigating the dipolar disorder mobility-reducing mechanism endemic to organic photorefractive materials and choosing transport agents that were relatively insensitive to this mechanism. We also synthesized dendrimers with design features further reducing dipolar disorder and also the significant van der Waals disorder for use in improved-speed photorefractive composites.
The future of information technology requires ultra high speed processing and large data storage capacity. Since the electronics technology using semi conduc tors and inorganic materials is about to reach its limits, much current research is focused on utilizing much faster photons than electrons, namely photonics. To achieve any significant effect on the actual use of the science of photonics, devel opments of more efficient photonics materials, better optical property evaluations, manufacture of devices for system applications, etc. are the subjects which need to be explored. In particular, the development of photonics materials stands in the forefront of research as this constitutes the most pertinent factor with regard to the development of ultra high speed and large capacity information processing. In this respect, there has been continuous research on photo responsive materials through molecular structure design and architecture and the results so far are very promising as functions and performances are beginning to realize their high expectations. The two special volumes "Polymers for Photonics Applications" give authorita tive and critical reviews on up to date activities in various fields of photonic poly mers including their promising applications. Seven articles have been contributed by internationally recognized and they deal with, polymers for second and third order nonlinear optics, quadratic parametric interactions in polymer waveguides, electroluminescent polymers as light sources, photoreflective polymers for holo graphic information storage, and highly efficient two photon absorbing organics and polymers.
Photorefractive polymer composites are an unusually sensitive class of photopolymers. Physics of Photorefraction in Polymers describes our current understanding of the physical processes that produce a photorefractive effect in key composite materials. Topics as diverse as charge generation, dispersive charge transport, charge compensation and trap
This book provides comprehensive, state-of-the art coverage of photorefractive organic compounds, a class of material with the ability to change their index of refraction upon illumination. The change is both dynamic and reversible. Dynamic because no external processing is required for the index modulation to be revealed, and reversible because the index change can be modified or suppressed by altering the illumination pattern. These properties make photorefractive materials very attractive candidates for many applications such as image restoration, correlation, beam conjugation, non-destructive testing, data storage, imaging through scattering media, holographic imaging and display. The field of photorefractive organic material is also closely related to organic photovoltaic and light emitting diode (OLED), which makes new discoveries in one field applicable to others.
This definitive guide to modern organic electro-optic and photonic technologies provides critical insight into recent advances in organic electro-optic materials, from the underlying quantum and statistical concepts through to the practical application of materials in modern devices and systems. • Introduces theoretical and experimental methods for improving organic electro-optic and photonic technologies • Reviews the central concepts of nonlinear optics, focusing on multi-scale theoretical methods • Provides clear insight into the structure and function relationships critical to optimizing the performance of devices based on organic electro-optic materials. Serving as a primer for the systematic nano-engineering of soft matter materials, this is an invaluable resource for those involved in the development of modern telecommunication, computing, and sensing technologies depending on electro-optic technology. It is also an indispensable work of reference for academic researchers and graduate students in the fields of chemistry, physics, electrical engineering, materials science and engineering, and chemical engineering.
This report describes our effort in the past three years on synthesis and characterization of novel photorefractive polymer system. Two major systems were developed, one of which combined the ionic transition metal complexes and a conjugated polymer backbone bearing NLO chromophores to manifest large photorefractive effect. Another is a molecular material containing oligothiophene and a nonlinear optical (NLO) chromophore. A large net optical gain (>200/cm) at a zero electric field was observed in the metal containing system. In the molecular system, a net optical gain of 83/cm and a diffraction efficiency of nearly 40% were obtained in a film made from this molecule under an applied field of 706 kv/cm. A fast response time of for the grating formation, 42 ms under 616 kv/cm, was observed.
Proceedings of SPIE present the original research papers presented at SPIE conferences and other high-quality conferences in the broad-ranging fields of optics and photonics. These books provide prompt access to the latest innovations in research and technology in their respective fields. Proceedings of SPIE are among the most cited references in patent literature.
"Furnishes the necessary background information, methods of characterization, and applications of optic and photonic systems based on polymers. Provides detailed tutorial chapters that offer in-depth explanations of optic and photonic fundamentals and synthesis techniques."