[PDF] Organosilicon Chemistry Ii eBook

Author : Vladimir Ya Lee
Publisher : Academic Press
Page : 758 pages
File Size : 15,63 MB
Release : 2017-08-22
Category : Science
ISBN : 0128019913

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Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry Covers important breakthroughs in the field, along with the historically significant achievements of the past Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology

Author : Norbert Auner (ed)
Publisher : Wiley-VCH
Page : 910 pages
File Size : 49,94 MB
Release : 1996
Category : Science
ISBN :

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Organosilicon Chemistry at its best... Like its hugely successful predecessor, this volume presents the latest developments in a rapidly developing field of industrial and academic research. Written by leading experts, it is a unique handbook for every scientist concerned with organosilicon compounds and their applications. From reviews of the first volume: 'The excellent presentation of its contents guarantees that it will occupy a prominent place within the literature on silicon chemistry.' Nachr. Chem. Lab. Techn. '... I do recommend this book highly to those scientists in academia and industry who are active in molecular organosilicon chemistry and/or silicon-based materials science.' Synthesis

Author : Bogdan Marciniec
Publisher : Taylor & Francis
Page : 620 pages
File Size : 33,23 MB
Release : 1995
Category : Chemical reactions
ISBN : 9782884491228

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Progress in Organosilicon Chemistry comprises more than thirty papers presented by many of the world's most eminent organosilicon specialists at the Tenth International Symposium on Organosilicon Chemistry held in Poznan, Poland in August 1993. The conference marked the fiftieth anniversary of the discovery and exploration of "direct synthesis." As much attention today is directed beyond silicon polymers, chemists have become involved with the use of elementary silicon and its applications, including ultrapure silicon in transistors and computers, silicon precursors of polymers, and other silicon-based materials as well as fine chemicals. This book provides an overview of organosilicon chemistry, including organic and inorganic chemistry of silicon, silicon polymers and oligomers; theoretical and structural chemistry of silicon; silicon-based materials and their applications; silicon in organic synthesis; mechanistic organosilicon chemistry; and bio- and environmental organosilicon chemistry. This diverse range of topics makes the book a valuable reference for chemists working in both applied and theoretical chemistry.

Author : Sam Stuart
Publisher : Elsevier
Page : 257 pages
File Size : 41,80 MB
Release : 2013-09-03
Category : Science
ISBN : 1483284824

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Organosilicon Chemistry: 2 provides information pertinent to the fundamental aspects of organosilicon chemistry. This book discusses the organosilicon substituents in anionic rearrangements as well as examines the production of tetrakis allene from a large number of aliphatic and aromatic polyhalogenated compounds. Organized into 14 chapters, this book begins with an overview of the use of organosilyl groups as migrating substituents. This text then examines the development in the chemistry of organosilicon cyclic compounds. Other chapters consider the evidence supporting the intermediacy of silylenes and the general picture of the chemistry of organosilylenes. This book discusses as well the two major approaches for the silylation of polyhalogenated compounds, including the direct reaction of polyhalogenated compounds and the metalation or halogen-metal exchange between the halogenated aromatic compounds and organolithium reagents. The final chapter deals with the importance of hydrosilation. This book is a valuable resource for chemists, scientists, and research workers.

Author : Norbert Auner
Publisher : John Wiley & Sons
Page : 371 pages
File Size : 11,24 MB
Release : 2011-09-22
Category : Science
ISBN : 3527620419

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Do you need to know what's new in organosilicon chemistry? This book provides in-depth coverage of the latest developments in this interdisciplinary and fast-evolving field: - selectivity and reactivity of organosilicon compounds - new synthetic applications - structure and bonding - applications in materials and polymer science Written by leading experts, this book is a well-referenced and critical overview of modern silicon chemistry. 'I recommend this book to the student and the practitioner in this new, very different, and very exciting field'. Eugene G. Rochow /Harvard University

Author : Vladimir Ya Lee
Publisher : Academic Press
Page : 1436 pages
File Size : 14,48 MB
Release : 2017-10-01
Category : Science
ISBN : 0128143630

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Organosilicon Compounds provides readers with the state-of-the-art status of organosilicon chemistry, including its theoretical, synthetic, physico-chemical and applied aspects. By including high quality content in a key strategic signing area, this work is a strong addition to chemistry offerings in organic, main group and organometallic research. Organosilicon chemistry deals with compounds containing carbon–silicon bonds, an essential part of organic and organometallic chemistry. This book presents the many milestone in the field that have been discovered during the last few years, also detailing its usage in commercial products, such as sealants, adhesives and coatings. Features valuable contributions from prominent experts who cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects Covers important breakthroughs in the field, along with historically significant achievements Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) working in organometallic, organosilicon, main group element, transition metal, industrial silicon chemistry, and more

Author : Tamejiro Hiyama
Publisher : John Wiley & Sons
Page : 566 pages
File Size : 14,47 MB
Release : 2020-02-18
Category : Science
ISBN : 3527344535

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Provides a unique summary of important catalytic reactions in the presence of silicon A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant metals. In addition to the topics covered above, Organosilicon Chemistry: Novel Approaches and Reactions features chapters that look at Lewis base activation of silicon Lewis acids, silylenes as ligands in catalysis, and chiral silicon molecules. -The first book about this topic in decades, covering a broad range of reactions -Covers new approaches and novel catalyst systems that have been developed in recent years -Written by well-known, international experts in the areas of organometallic silicon chemistry and organosilicon cross-coupling reactions Organosilicon Chemistry: Novel Approaches and Reactions is an indispensable source of information for synthetic chemists in academia and industry, working in the field of organic synthesis, catalysis, and main-group chemistry.

Author : Norbert Auner
Publisher : John Wiley & Sons
Page : 742 pages
File Size : 21,75 MB
Release : 2008-08-29
Category : Science
ISBN : 3527620745

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Organosilicon Chemistry at its best ...((kursiv)) Like its two hugely successful predecessors, the third volume again presents the latest developments in a rapidly developing field of industsrial and academic research. The contributions from approx. 80 internationally renowned experts and researchers in this fascinating part of the rapidly growing field of main group chemistry describe current trends in organosilicon chemistry and provide summaries of the latest (1997!) knowledge in this area. To facilitate access to the ongoing research this volume is split into two parts, each with a comprehensive introduction: Part 1: Fascinating Organosilicon Compounds Part 2: Silicon Based Materials

Author : Norbert Auner
Publisher : Wiley-VCH
Page : 0 pages
File Size : 17,12 MB
Release : 2003-12-09
Category : Science
ISBN : 9783527306701

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Never Change a winning team. The fifth volume in this renowned series retains the established and successful concept: Leading experts from academia and industry present a comprehensive and detailed overview of the latest results in organosilicon chemistry. Synthesis and characterization of new organosilicon compounds Applications in polymer and materials science Summary of the latest research results The result is a unique collection of first-hand information, vital for every expert working in this field. From the contents: Reactions of Silicon Atoms- An Access to Unusual Molecules New Reactions of Stable Silylenes Synthesis and Chemistry of Some Bridged Silicocations Synthesis of a Highly Enantiomerically Enriched Silyllithium Compound Experimental Determination of the Inversion Barriers of Oligosily Anions SiO and SiOSiN Chains, Rings, and Cages Novel Cyclic and Polycyclic Chalcogenides of Silicon Organosilicon Compounds in Medicine and Cosmetics Organosilicon Chemistry and Nanoscience Sustainable Silicon Production The Role of Silanes in Filled and Crosslinked Polymers Catalytic Hydrosilylation of Fatty Compounds Novel Routes fro the Preparation of Nanoporous Silica Particles Aluminosiloxanes as Molecular Models for Aluminosilicates