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Atomic and Molecular Clusters

Author : Roy L. Johnston
Publisher : CRC Press
Page : 258 pages
File Size : 32,13 MB
Release : 2002-04-25
Category : Science
ISBN : 9781420055771

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Cluster physics is the foundation of the increasingly important field of nanotechnology. Clusters, ranging in size from a few to many millions of atoms, constitute a fascinating field of research in physics, chemistry and materials science. They are formed by most of the elements of the Periodic Table, and the types of bonding and the resultant clusters are equally as varied. This book introduces atomic clusters, ranging from weakly-bonded clusters of argon to strongly-bonded carbon clusters and metal nano-particles. It includes worked examples to enable lecturers and students to gauge their understanding and progress. Atomic and Molecular Clusters describes the experimental generation, detection and interrogation of clusters and theoretical approaches developed to aid understanding of their physical properties. It classifies clusters according to their bonding types and gives examples of present and possible future applications of clusters in electronic, optical and magnetic devices.

Molecular Clusters

Author : Thomas Fehlner
Publisher : Cambridge University Press
Page : 388 pages
File Size : 24,12 MB
Release : 2007-07-05
Category : Science
ISBN : 1107320836

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Clusters can be viewed as solids at the nano-scale, yet molecular cluster chemistry and solid state chemistry have traditionally been considered as separate topics. This treatment has made it conceptually difficult to appreciate commonalities of structure and bonding between the two. Using analogous models, this is the first book to form a connecting bridge. Although the focus is on clusters, sufficient attention is paid to solid-state compounds at each stage of the development to establish the interrelationship between the two topics. Comprehensive coverage of cluster types by composition, size and ligation, is provided, as is a synopsis of selected research. Written in an accessible style and highly illustrated to aid understanding, this book is suitable for researchers in inorganic chemistry, physical chemistry, materials science, and condensed matter physics.

Theory of Atomic and Molecular Clusters

Author : Julius Jellinek
Publisher : Springer Science & Business Media
Page : 438 pages
File Size : 25,61 MB
Release : 2012-12-06
Category : Science
ISBN : 364258389X

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The emergence and spectacularly rapid evolution of the field of atomic and molecular clusters are among the most exciting developments in the recent history of natural sciences. The field of clusters expands into the traditional disciplines of physics, chemistry, materials science, and biology, yet in many respects it forms a cognition area of its own. This book presents a cross section of theoretical approaches and their applications in studies of different cluster systems. The contributions are written by experts in the respective areas. The systems discussed range from weakly (van der Waals) bonded, through hydrogen- and covalently bonded, to semiconductor and metallic clusters. The theoretical approaches involve high-level electronic structure computations, more approximate electronic structure treatments, use of semiempirical potentials, dynamical and statistical analyses, and illustrate the utility of both classical and quantum mechanical concepts.

Molecular Clusters of the Main Group Elements

Author : Matthias Driess
Publisher : John Wiley & Sons
Page : 460 pages
File Size : 22,29 MB
Release : 2008-11-21
Category : Science
ISBN : 3527614370

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With more than 20 contributions from leading research groups, this book provides essential information for chemists and materials scientists working with molecular clusters. It treats both homonuclear and heteronuclear clusters, including: the theory and concepts in main-group cluster chemistry, * novel boranes and heteroboranes, * silicon/germanium/tin clusters, * alkali metal suboxides, * clusters in alloys with mercury, * chalkogen clusters * and numerous other compound classes. The whole is illustrated by examples of the great potential for technical applications such as electron storage, cancer therapy and in optoelectronic devices. Its systematic coverage of all relevant main group elements makes this the prime reference source in the field.

Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields

Author : Youngwook Park
Publisher : Springer Nature
Page : 41 pages
File Size : 19,73 MB
Release : 2020-10-01
Category : Science
ISBN : 9811586934

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This book describes the manipulation of molecular properties, such as orientation, structure, and dynamics, of small molecules and molecular clusters isolated in cold inert matrices by using unprecedentedly strong external electrostatic fields. Manipulation of molecules with controllable external forces is a dream of chemists. Molecules are inherently quantum-mechanical systems, control of which potentially can lead to quantum technology, such as quantum sensing and computing. This book demonstrates a combination of the ice film nanocapacitor method and the matrix isolation technique enabled the application of intense external dc electric fields across the isolated molecules and molecular clusters. Changes in molecular states induced by fields were monitored by means of vibrational spectroscopy. Also, the book presents manipulations of the inversion tunneling dynamics of ammonia molecule and the dislocation of acidic proton in hydrogen chloride–water complex. The book shows that the vibrational spectroscopy with the aid of unprecedentedly strong dc electric field can provide rich information on the electrostatic behaviors of molecules and molecular clusters, which underlie the understanding of intermolecular processes and molecular manipulation.

Theory of Atomic and Molecular Clusters

Author : Julius Jellinek
Publisher : Springer Science & Business Media
Page : 444 pages
File Size : 32,8 MB
Release : 1999
Category : Science
ISBN : 9783540620006

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The book summarises contemporary knowledge about the theory of atomic and molecular clusters. New results are discussed on a high theoretical level. Access to this field of research is given by an explanation of the various subjects in introductory chapters.

Clusters of Atoms and Molecules

Author : Hellmut Haberland
Publisher : Springer Science & Business Media
Page : 435 pages
File Size : 21,20 MB
Release : 2013-11-11
Category : Science
ISBN : 3642843298

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Clusters of Atoms and Molecules I is devoted to theoretical concepts and experimental techniques important in the rapidly expanding field of cluster science. Cluster properties are dicussed for clusters composed of alkali metals, semiconductors, transition metals, carbon, oxides and halides of alkali metals, rare gases, and neutral molecules. The book contains several well-integrated treatments, all prepared by experts. Each contribution starts out as simple as possible and ends with the latest results, so that the book can serve as a text for a course, an introduction into the field, or as a reference book for the expert.

Large Clusters of Atoms and Molecules

Author : T.P. Martin
Publisher : Springer Science & Business Media
Page : 539 pages
File Size : 17,28 MB
Release : 2012-12-06
Category : Science
ISBN : 9400902115

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Proceedings of the NATO Advanced Study Institute, Erice, Sicily, Italy, June 19-29, 1995

Atoms, Molecules and Clusters in Electric Fields

Author : George Maroulis
Publisher : Imperial College Press
Page : 694 pages
File Size : 35,86 MB
Release : 2006
Category : Technology & Engineering
ISBN : 1860948863

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With the central importance of electric polarizability and hyperpolarizability for a wide spectrum of activities, this book charts the trends in the accurate theoretical determination of these properties in specialized fields. The contributions include reviews and original papers that extend from methodology to applications in specific areas of primary importance such as cluster science and organic synthesis of molecules with specific properties.