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Completely revised and expanded throughout, Mixed Surfactant Systems, Second Edition surveys the latest results, newest experimental perspectives, and theoretical investigations of properties, behavior, and techniques applicable to mixed surfactant systems. This important book elucidates core theoretical notions while summarizing results of
Completely revised and expanded throughout, Mixed Surfactant Systems, Second Edition surveys the latest results, newest experimental perspectives, and theoretical investigations of properties, behavior, and techniques applicable to mixed surfactant systems. This important book elucidates core theoretical notions while summarizing results of cutting-edge studies in nanoscale phase separation at monolayers of mixed amphiphiles, nanocapsule preparation through mixtures of cationic and anionic polymer amphiphiles, and the photodegradation of mixed surfactant systems by titanium dioxide. The book provides new sections on topics including: Diffusion of mixed micelles Mixed micelles of fluorinated and conventional surfactants Sponge-like vesicles of mixed surfactants Liquid crystals of mixed surfactants Mixtures of surfactants and polymers Photolysis of mixed surfactants Reflecting the abundance of current and emerging applications in the field, Mixed Surfactant Systems, Second Edition compiles chapters written by world-renowned leaders in industry for an up-to-date scientific account of the dynamics of mixed surfactant systems, including physicochemical properties and behavior of surfactant mixtures in detergency and surfactant precipitation.
Presents a broad survey of the properties, behavior, and modeling of mixed surfactant systems, including mixed micellar solutions, phenomena at interfaces, phase behavior, and mixtures with unusual surfactant types. Covers chemical reactions in mixed micelles, approaches to molecular modeling of mixed surfactant aggregates, and new experimental techniques for studying mixed micelles and adsorption on surfaces. Features contributions from leading specialists in colloid and surface science, including Robert S. Schechter, John F. Scamehorn, Milton J. Rosen, Keizo Ogino, and Denver G. Hall.
This work describes the solubility, solution properties, thermodynamics, miscibility, solubilization, mesomorphic character and other physical properties of mixed surfactant systems - presenting both theoretical analysis and a wide range of practical applications. Equations clarify complex and abstract constructs.;The book also: treats mixed critical micelle concentrations, surface tension, flotation and absorption in terms of thermodynamic models; explores the miscibility of fluorocarbon and hydrocarbon surfactants in the micelles, covering micelle formation, liquid-liquid solubility and thermodynamics of mixed micellization; determines the mean aggregation number by steady-state quenching methods, and analyzes the composition of mixed micelles; discusses the mechanisms and experimental studies of adsorption from mixed surfactant systems; examines surface activity of surfactant mixtures, mixing phenomena and liquid crystal phase behaviour; and reviews means of investigation that use ion-specific electrodes, light scattering, and NMR and flourescence probing.
"Second Edition provides a thorough, up-to-date treatment of the fundamental behavior of surface active agents in solutions, their interaction with biological structures from proteins and membranes to the stratum corneum and epidermis, and their performance in formulations such as shampoos, dentifrice, aerosols, and skin cleansers."
This book gives the reader an introduction to the field of surfactants in solution as well as polymers in solution. Starting with an introduction to surfactants the book then discusses their environmental and health aspects. Chapter 3 looks at fundamental forces in surface and colloid chemistry. Chapter 4 covers self-assembly and 5 phase diagrams. Chapter 6 reviews advanced self-assembly while chapter 7 looks at complex behaviour. Chapters 8 to 10 cover polymer adsorption at solid surfaces, polymers in solution and surface active polymers, respectively. Chapters 11 and 12 discuss adsorption and surface and interfacial tension, while Chapters 13- 16 deal with mixed surfactant systems. Chapter 17, 18 and 19 address microemulsions, colloidal stability and the rheology of polymer and surfactant solutions. Wetting and wetting agents, hydrophobization and hydrophobizing agents, solid dispersions, surfactant assemblies, foaming, emulsions and emulsifiers and microemulsions for soil and oil removal complete the coverage in chapters 20-25.
"Provides comprehensive coverage of the synthesis, analysis, application, and chemical and physical properties of amphoteric surfactants--furnishing an up-to-date account of important new developments. Details the application of amphoteric surfactants in personal care products and household and industrial detergents."