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This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. Provides a general background as a course module in the area of inorganic reaction mechanisms, which has important research applications in the metallurgical industry Contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands
Ideal for newcomers and established researchers in the field Reaction Mechanisms of Metal Complexes in Solution is a complete treatment of the area covering advanced topics with relevance to biomedical applications, extraction metallurgy, food chemistry and a wealth of other industrial processes and research areas.
Ralph G. Wilkins Kinetics and Mechanism of Reactions of Transition Metal Complexes This thoroughly revised and updated edition of one of the classics of kinetics textbooks continues the successful concept of the 1974 edition. It starts with a simplified approach to the determination of rate laws and mechanisms, steadily working up to complex situations. In the following chapters the principles developed there are extensively used in a comprehensive account of reactions of transition metal complexes, including reactions of biological significance. The text is illustrated by numerous figures and tables. Points of further interest are highlighted in special insets. 140 problems, taken from the original literature, enable the student to apply and deepen the newly acquired knowledge and make the book highly useful for courses in inorganic and organometallic reaction mechanisms. Furthermore, a wealth of over 1700 references make the book indispensable for the active researcher.
The reading journey of this book starts with very important phenomenon in inorganic chemistry known as the Trans effect. The Trans effect then leads to a very fascinating discovery that changed the whole world. That was the discovery of the anti-cancer drug. The story of its invention is really interesting. This will really trigger the minds of students that how inventions are made. This will show you how one invention leads path to the other. This book introduces the work of Nobel Prize winners and scientist who dedicated their whole life for the sake of chemistry. Henry Taube was awarded the Nobel Prize for his work on complexes & outer and inner sphere reaction mechanism. This book introduces his work. Rudolf A. Marcus received Nobel Prize for his work on redox reactions in complexes. This book discusses the basic principles of redox reactions in complexes. Transition metal complexes plays a fundamental role in three important areas. (1) Bioinorganic chemistry (2) Medicinal chemistry (3) Industrial chemistry. The study of the mechanism helps in designing new inorganic materials, new inorganic catalysts, and new inorganic medicines and for understanding the biological processes. This is a simple book discussing basic principles of inorganic reaction mechanisms. Further, we have provided minor information about basic bioinorganic reactions, nuclear reactions and the chain reaction mechanism. The phenomenon such as acid rain has also been discussed. The last chapter classifies the reactions of metal complexes. Hope this book will be useful for science graduates and post graduates and also for the engineering students.
Jetzt in neuer Auflage: Das erfolgreiche Lehrwerk über Kinetik und Mechanismen anorganischer und organometallischer Reaktionen für fortgeschrittene Studenten! Hervorragend geeignet als Begleiter eines Vorlesungssemesters. Mit zahlreichen Übungsaufgaben; für eine bessere Übersicht sorgen Zusammenfassungen am Ende jedes Kapitels.
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Reaction Mechanisms of Metal Complexes in Solution provides a comprehensive overview of an often-overlooked research area. Despite its importance and recent reshaping of the field, many inorganic chemists have lost an appreciation for the significance of stability constants and the thermodynamic aspects of complex formation. Ideal for newcomers and established researchers in the field this book is a complete treatment of the area covering advanced topics with relevance to biomedical applications, extraction metallurgy, food chemistry and a wealth of other industrial processes and research areas. The book will be of particular interest to postgraduates with an interest in coordination chemistry, catalysis, supramolecular chemistry, metallobiology and related aspects of biochemistry.
Understanding the mechanisms of the reactions at transition metal sites is a key component in designing synthetic methods, developing industrial homogeneous catalysts, and investigating metalloenzymes. These mechanisms are therefore an essential part of undergraduate chemistry courses. This primer provides a broad-based, systematic guide to the fundamentals of transition-metal mechanistic chemistry, including substitution, electron transfer, and reactions of ligands. It serves as an ideal text for undergraduate students with a foundation in basic inorganic chemistry but who are new to inorganic reaction mechanisms.
Homogeneous catalysis by soluble metal complexes has gained considerable attention due to its unique applications and features such as high activity and selectivity. Catalysis of this type has demonstrated impressive achievements in synthetic organic chemistry and commercial chemical technology. Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms presents a comprehensive summary of the results obtained over the last sixty years in the field of the kinetics and mechanisms of organic and inorganic reactions catalyzed with metal complexes. Topics covered include: Specific features of catalytic reaction kinetics in the presence of various mono- and polynuclear metal complexes and nanoclusters Multi-route mechanisms and the methods of their identification, as well as approaches to the kinetics of polyfunctional catalytic systems Principles and features of the dynamic behavior of nonlinear kinetic models The potential, achievements, and limitations of applying the kinetic approach to the identification of complex reaction mechanisms The development of a rational strategy for designing kinetic models The kinetic models and mechanisms of many homogeneous catalytic processes employed in synthetic and commercial chemistry Written for specialists in the field of kinetics and catalysis, this book is also relevant for post-graduates engaged in the study
A comprehensive coverage of reaction mechanisms of metal complexes in solution. Reflecting the latest developments in the field, one of the features of the book is a chapter on practical kinetics.