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Providing a range of information on polymers and polymerization techniques, this text covers the gamut of polymer science from synthesis, structure and properties to function and applications. It analyzes speciality polymers, including acrylics, fluoropolymers, polysiplanes, polyphosphazenes, and inorganic and conducting polymers. The book examines the stereochemistry of polymerization and the stereoregularity of polymers.
Macromolecular Engineering: Design, Synthesis and Application of Polymers explores the role of macromolecular engineering in the development of polymer systems with engineered structures that offer the desired combination of properties for advanced applications. This book is organized into sections covering theory and principles, science and technology, architectures and technologies, and applications, with an emphasis on the latest advances in techniques, materials, properties, and end uses - and including recently commercialized, or soon to be commercialized, designed polymer systems. The chapters are contributed by a group of leading figures who are actively researching in the field. This is an invaluable resource for researchers and scientists interested in polymer synthesis and design, across the fields of polymer chemistry, polymer science, plastics engineering, and materials science and engineering. In industry, this book supports engineers, R&D, and scientists working on polymer design for application areas such as biomedical and healthcare, automotive and aerospace, construction and consumer goods. Presents the theory, principles, architectures, technologies, and latest advances in macromolecular engineering for polymer design and synthesis Explains polymer design for cutting-edge applications areas, including coatings, automotive, industrial, household and medical uses Approaches several novel materials, such as polyisobutylene (PIB), polyamide-based polyurethanes, and aliphatic polyesters
The field of CMA (complex macromolecular architecture) stands at the cutting edge of materials science, and has been a locus of intense research activity in recent years. This book gives an extensive description of the synthesis, characterization, and self-assembly of recently-developed advanced architectural materials with a number of potential applications. The architectural polymers, including bio-conjugated hybrid polymers with poly(amino acid)s and gluco-polymers, star-branched and dendrimer-like hyperbranched polymers, cyclic polymers, dendrigraft polymers, rod-coil and helix-coil block copolymers, are introduced chapter by chapter in the book. In particular, the book also emphasizes the topic of synthetic breakthroughs by living/controlled polymerization since 2000. Furthermore, renowned authors contribute on special topics such as helical polyisocyanates, metallopolymers, stereospecific polymers, hydrogen-bonded supramolecular polymers, conjugated polymers, and polyrotaxanes, which have attracted considerable interest as novel polymer materials with potential future applications. In addition, recent advances in reactive blending achieved with well-defined end-functionalized polymers are discussed from an industrial point of view. Topics on polymer-based nanotechnologies, including self-assembled architectures and suprastructures, nano-structured materials and devices, nanofabrication, surface nanostructures, and their AFM imaging analysis of hetero-phased polymers are also included. Provides comprehensive coverage of recently developed advanced architectural materials Covers hot new areas such as: click chemistry; chain walking; polyhomologation; ADMET Edited by highly regarded scientists in the field Contains contributions from 26 leading experts from Europe, North America, and Asia Researchers in academia and industry specializing in polymer chemistry will find this book to be an ideal survey of the most recent advances in the area. The book is also suitable as supplementary reading for students enrolled in Polymer Synthetic Chemistry, Polymer Synthesis, Polymer Design, Advanced Polymer Chemistry, Soft Matter Science, and Materials Science courses. Color versions of selected figures can be found at www.wiley.com/go/hadjichristidis
Plastics are used worldwide in everyday life, e.g. as food packaging, electronics, construction, automotive parts, and household appliances. To produce these products with the desired service lifetimes the use of suitable stabilizers is necessary. This book provides a concise and comprehensive overview of the basic mechanisms of plastic degradation processes caused by heat and light. At its core is a detailed description of the stabilization of different polymers, including an explanation of stabilization mechanisms and the influence of commonly used additives such as fillers, flame retardents and pigments on the stability of plastic. Every polymer scientist, material technologist, or application engineer dealing with the design of the properties of plastics will benefit from this new overview.
Macromolecular Engineering: Design, Synthesis and Application of Polymers explores the role of macromolecular engineering in the development of polymer systems with engineered structures that offer the desired combination of properties for advanced applications. This book is organized into sections covering theory and principles, science and technology, architectures and technologies, and applications, with an emphasis on the latest advances in techniques, materials, properties, and end uses – and including recently commercialized, or soon to be commercialized, designed polymer systems. The chapters are contributed by a group of leading figures who are actively researching in the field. This is an invaluable resource for researchers and scientists interested in polymer synthesis and design, across the fields of polymer chemistry, polymer science, plastics engineering, and materials science and engineering. In industry, this book supports engineers, R&D, and scientists working on polymer design for application areas such as biomedical and healthcare, automotive and aerospace, construction and consumer goods. Presents the theory, principles, architectures, technologies, and latest advances in macromolecular engineering for polymer design and synthesis Explains polymer design for cutting-edge applications areas, including coatings, automotive, industrial, household and medical uses Approaches several novel materials, such as polyisobutylene (PIB), polyamide-based polyurethanes, and aliphatic polyesters
Molecular manipulation of nano- and microstructures paves the way to produce organic polymer materials by design. Such architectures comprise both the synthesis and the kinetics and thermodynamics of macromolecular organization and is the theme of this volume. The book consists of four articles reviewing living polymerization to produce precisely defined linear polyesters, comparing them to other living polymerization techniques. The articles also deal with the synthesis of polymeric dendrimers, either by the convergent or divergent approach; block copolymers synthesis, to define micromorphology in high performance polymers; and thereby tailoring their thermal, chemical, mechanical and dielectrical properties, and finally kinetics and thermodynamics for microstructural organization in macroporous thermosets.
Introduction to Macromolecular Science provides a broad introduction to polymer science, including polymer structure, techniques for synthesis, properties in solution, and the technology of polymeric materials. This revised Second Edition presents up-to-date information on the newest aspects of polymer science, as well as expanded, comprehensive treatments of foundational techniques and theories. Additionally, each chapter concludes with a list of references for further research, a set of review questions, and a list of theoretical derivations and numerical problems. Other new features of this edition include: Coverage of recent synthetic procedures for polymers, such as living radical and cationic polymerizations, group transfer polymerization, polymerizations using metallocene and metathesis catalysts, and syntheses leading to dendrimers Expanded material on separation techniques and the technological facets of polymer processing An introduction to the techniques used for studying the structure of nucleic acids Techniques for studying polymer surfaces and polymeric membranes Topics such as polymer nomenclature, liquid crystalline polymers, and block copolymer micelles Introduction to Macromolecular Science, Second Edition is an essential volume for students and scholars of chemistry and chemical engineering, as well as polymer researchers, chemists, and chemical engineers in government and industry.
How can a scientist or engineer synthesize and utilize polymers to solve our daily problems? This introductory text, aimed at the advanced undergraduate or graduate student, provides future scientists and engineers with the fundamental knowledge of polymer design and synthesis to achieve specific properties required in everyday applications. In the first five chapters, this book discusses the properties and characterization of polymers, since designing a polymer initially requires us to understand the effects of chemical structure on physical and chemical characteristics. Six further chapters discuss the principles of polymerization reactions including step, radical chain, ionic chain, chain copolymerization, coordination and ring opening. Finally, material is also included on how commonly known polymers are synthesized in a laboratory and a factory. This book is suitable for a one semester course in polymer chemistry and does not demand prior knowledge of polymer science.
Molecular manipulation of nano- and microstructures paves the way to produce organic polymer materials by design. Such architectures comprise both the synthesis and the kinetics and thermodynamics of macromolecular organization and is the theme of this volume. The book consists of four articles reviewing living polymerization to produce precisely defined linear polyesters, comparing them to other living polymerization techniques. The articles also deal with the synthesis of polymeric dendrimers, either by the convergent or divergent approach; block copolymers synthesis, to define micromorphology in high performance polymers; and thereby tailoring their thermal, chemical, mechanical and dielectrical properties, and finally kinetics and thermodynamics for microstructural organization in macroporous thermosets.