[PDF] Low Temperature Combustion With Thermo Chemical Recuperation To Maximize In Use Engine Efficiency eBook

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File Size : 10,39 MB
Release : 2009
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The key to overcome Low Temperature Combustion (LTC) load range limitations in reciprocating engines is based on proper control over the thermo-chemical properties of the in-cylinder charge. The studied alternative to achieve the required control of LTC is the use of two separate fuel streams to regulate timing and heat release at specific operational points, where the secondary fuel is a reformed product of the primary fuel in the tank. It is proposed in this report that the secondary fuel can be produced using exhaust heat and Thermo-Chemical Recuperation (TCR). TCR for reciprocating engines is a system that employs high efficiency recovery of sensible heat from engine exhaust gas and uses this energy to transform fuel composition. The recuperated sensible heat is returned to the engine as chemical energy. Chemical conversions are accomplished through catalytic and endothermic reactions in a specially designed reforming reactor. An equilibrium model developed by Gas Technology Institute (GTI) for heptane steam reforming was applied to estimate reformed fuel composition at different reforming temperatures. Laboratory results, at a steam/heptane mole ratio less than 2:1, confirm that low temperature reforming reactions, in the range of 550 K to 650 K, can produce 10-30% hydrogen (by volume, wet) in the product stream. Also, the effect of trading low mean effective pressure for displacement to achieve power output and energy efficiency has been explored by WVU. A zerodimensional model of LTC using heptane as fuel and a diesel Compression Ignition (CI) combustion model were employed to estimate pressure, temperature and total heat release as inputs for a mechanical and thermal loss model. The model results show that the total cooling burden on an LTC engine with lower power density and higher displacement was 14.3% lower than the diesel engine for the same amount of energy addition in the case of high load (43.57mg fuel/cycle). These preliminary modeling and experimental results suggest that the LTC-TCR combination may offer a high efficiency solution to engine operation. A single zone model using a detailed chemical kinetic mechanism was implemented in CHEMKIN and to study the effects of base fuel and steam-fuel reforming products on the ignition timing and heat release characteristics. The study was performed considering the reformed fuel species composition for total n-heptane conversion (ideal case) and also at the composition corresponding to a specific set of operational reforming temperatures (real case). The computational model confirmed that the reformed products have a strong influence on the low temperature heat release (LTHR) region, affecting the onset of the high temperature heat release (HTHR). The ignition timing was proportionally delayed with respect to the baseline fuel case when higher concentrations of reformed gas were used. For stoichiometric concentration of RG, it was found that by increasing the proportion of reformed fuel to total fuel (RG), from 0% to 30%, the amount of energy released during the LTHR regime, or HR{sub L}, was reduced by 48% and the ignition timing was delayed 10.4 CA degrees with respect to the baseline fuel case. For RG composition corresponding to certain operational reforming temperatures, it was found that the most significant effects on the HCCI combustion, regarding HR{sub L} reduction and CA50 delay, was obtained by RG produced at a reforming temperature range of 675 K-725 K.

Author : P. A. Lakshminarayanan
Publisher : Springer Nature
Page : 562 pages
File Size : 20,97 MB
Release : 2022-01-01
Category : Technology & Engineering
ISBN : 9811685703

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This handbook deals with the vast subject of thermal management of engines and vehicles by applying the state of the art research to diesel and natural gas engines. The contributions from global experts focus on management, generation, and retention of heat in after-treatment and exhaust systems for light-off of NOx, PM, and PN catalysts during cold start and city cycles as well as operation at ultralow temperatures. This book will be of great interest to those in academia and industry involved in the design and development of advanced diesel and CNG engines satisfying the current and future emission standards.

Author : Flavio Dal Forno Chuahy
Publisher :
Page : 0 pages
File Size : 32,40 MB
Release : 2018
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Dual fuel reactivity controlled compression ignition (RCCI) combustion is a promising method to achieve high efficiency with near zero NOx and soot emissions; however, the requirement to carry two fuels on-board has limited practical applications. Advancements in catalytic reforming have demonstrated the ability to generate syngas (a mixture of CO and hydrogen) from a single hydrocarbon stream. The reformed fuel mixture can then be used as a low reactivity fuel stream to enable RCCI out of a single parent fuel. Beyond enabling dual-fuel combustion strategies out of a single parent fuel, fuel reforming can be endothermic and allow recovery of exhaust heat to drive the reforming reactions, potentially improving overall efficiency of the system. Previous works have focused on using reformed fuel to extend the lean limit of spark ignited engines, and enhancing the control of HCCI type combustion. The strategy pairs naturally with advanced dual-fuel combustion strategies, and the use of dual-fuel strategies in the context of on-board reforming and energy recovery has not been explored. Accordingly, the work presented in this dissertation attempts to fill in the gaps in the current literature and provide a pathway to "single" fuel RCCI combustion through a combination of experiments and computational fluid dynamics modeling. Initially, a system level analysis focusing on three common reforming techniques (i.e., partial oxidation, steam reforming and auto-thermal reforming) was conducted to evaluate the potential of reformed fuel. A system layout was proposed for each reforming technique and a detailed thermodynamic analysis using first- and second-law approaches were used to identify the sources of efficiency improvements. The results showed that reformed fuel combustion with a near TDC injection of diesel fuel can increase engine-only efficiency by 4% absolute when compared to a conventional diesel baseline. The efficiency improvements were a result of reduced heat transfer and shorter, more thermodynamically efficient, combustion process. For exothermic reforming processes, losses in the reformer outweigh the improvements to engine efficiency, while for endothermic processes the recovery of exhaust energy was able to allow the system efficiency to retain a large portion of the benefits to the engine combustion. Energy flow analysis showed that the reformer temperature and availability of high grade exhaust heat were the main limiting factors preventing higher efficiencies. RCCI combustion was explored experimentally for its potential to expand on the optimization results and achieve low soot and NOx emissions. The results showed that reformed fuel can be used with diesel to enable RCCI combustion and resulted in low NOx and soot emissions while achieving efficiencies similar to conventional diesel combustion. Experiments showed that the ratio H2/(H2+CO) is an important parameter for optimal engine operation. Under part-load conditions, fractions of H2/(H2+CO) higher than 60% led to pressure oscillations inside the cylinder that substantially increased heat transfer and negated any efficiency benefits. The system analysis approach was applied to the experimental results and showed that chemical equilibrium limited operation of the engine to sub-optimal operating conditions. RCCI combustion was able to achieve "diesel like" system level efficiencies without optimization of either the engine operating conditions or the combustion system. Reformed fuel RCCI was able to provide a pathway to meeting current and future emission targets with a reduction or complete elimination of aftertreatment costs. Particle size distribution experiments showed that addition of reformed fuel had a significant impact on the shape of the particle size distribution. Addition of reformed fuel reduced accumulation-mode particle concentration while increasing nucleation-mode particles. When considering the full range of particle sizes there was a significant increase in total particle concentration. However, when considering currently regulated (Dm>23nm) particles, total concentration was comparable. To address limitations identified in the system analysis of the RCCI experiments a solid oxide fuel cell was combined with the engine into a hybrid electrochemical combustion system. The addition of the fuel cell addresses the limitations by providing sufficient high grade heat to fully drive the reforming reactions. From a system level perspective, the impact of the high frequency oscillations observed in the experiments are reduced, as the system efficiency is less dependent on the engine efficiency. From an engine perspective, the high operating pressures and low reactivity of the anode gas allow reduction of the likelihood of such events. A 0-D system level code was developed and used to find representative conditions for experimental engine validation. The results showed that the system can achieve system electrical efficiencies higher than 70% at 1 MWe power level. Experimental validation showed that the engine was able to operate under both RCCI and HCCI combustion modes and resulted in low emissions and stable combustion. The potential of a hybrid electrochemical combustion system was demonstrated for high efficiency power generation

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File Size : 45,65 MB
Release : 2009
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The objective of the University consortium was to investigate the fundamental processes that determine the practical boundaries of Low Temperature Combustion (LTC) engines and develop methods to extend those boundaries to improve the fuel economy of these engines, while operating with ultra low emissions. This work involved studies of thermal effects, thermal transients and engine management, internal mixing and stratification, and direct injection strategies for affecting combustion stability. This work also examined spark-assisted Homogenous Charge Compression Ignition (HCCI) and exhaust after-treatment so as to extend the range and maximize the benefit of Homogenous Charge Compression Ignition (HCCI)/ Partially Premixed Compression Ignition (PPCI) operation. In summary the overall goals were; Investigate the fundamental processes that determine the practical boundaries of Low Temperature Combustion (LTC) engines; Develop methods to extend LTC boundaries to improve the fuel economy of HCCI engines fueled on gasoline and alternative blends, while operating with ultra low emissions; and Investigate alternate fuels, ignition and after-treatment for LTC and Partially Premixed compression Ignition (PPCI) engines.

Author : Bernard Desmet
Publisher : John Wiley & Sons
Page : 260 pages
File Size : 20,20 MB
Release : 2022-11-30
Category : Science
ISBN : 1394188188

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Optimizing the process of converting heat into mechanical power is a major challenge when it comes to meeting targets for protecting primary energy resources and minimizing our environmental impact. For many years to come, the use of thermal engines will continue to be necessary for transportation on land, by sea and by air, as well as for many industrial applications. Against this background, Thermodynamics of Heat Engines aims to present a comprehensive overview of the thermodynamic concepts, including combustion, that are necessary for understanding the phenomena governing the energy efficiency of internal and external combustion engines as well as that of gas turbines and jet propulsion engines. Existing and developing industrial applications, based on combined heat and power (CHP) or the use of staged cycles, are presented, with particular attention paid to the recovery of low temperature waste heat. This book, which is mainly intended for university and engineering students but is also useful for engineers and technicians working in the fields concerned, provides a basis for reflection on the optimization of energy systems.

Author : Prabhat Ranjan Jha
Publisher :
Page : 313 pages
File Size : 21,99 MB
Release : 2020
Category : Electronic dissertations
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It's crucial to use advanced combustion strategies to increase efficiency and decrease engine-out pollutants because of the compelling need to reduce the global carbon footprint. This dissertation proposes dual fuel low-temperature combustion as a viable strategy to decrease engine-out emissions and increase the thermal efficiency of future heavy-duty internal combustion (IC) engines. In dual fuel combustion, a low reactivity fuel (e.g. methane, propane) is ignited by a high reactivity fuel (diesel) in a compression-ignited engine. Generally, the energy fraction of low reactivity fuel is maintained at much higher levels than the energy fraction of the high reactivity fuel. For a properly calibrated engine, combustion occurs at lean and low-temperature conditions (LTC). This decreases the chances of the formation of soot and oxides of nitrogen within the engine. However, at low load conditions, this type of combustion results in high hydrocarbon and carbon monoxide emissions. The first part of this research experimentally examines the effect of methane (a natural gas surrogate) substitution on early injection dual fuel combustion at representative low loads of 3.3 and 5.0 bar BMEPs in a single-cylinder compression ignition engine (SCRE). Gaseous methane fumigated into the intake manifold at various methane energy fractions was ignited using a high-pressure diesel pilot injection at 310 CAD. Cyclic combustion variations at both loads were also analyzed to obtain further insights into the combustion process and identify opportunities to further improve fuel conversion efficiencies at low load operation. In the second part, the cyclic variations in dual fuel combustion of three different low reactivity fuels (methane, propane, and gasoline) ignited using a high-pressure diesel pilot injection was examined and the challenges and opportunities in utilizing methane, propane, and gasoline in diesel ignited dual fuel combustion, as well as strategies for mitigating cyclic variations, were explored. Finally, in the third part a CFD model was created for diesel methane dual fuel LTC. The validated model was used to investigate the effect of methane on diesel autoignition and various spray targeting strategies were explored to mitigate high hydrocarbon and carbon monoxide emissions at low load conditions.

Author : David R. Vernon
Publisher :
Page : pages
File Size : 45,80 MB
Release : 2010
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ISBN : 9781124509464

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The thermochemical recuperation process uses endothermic reformation reactions to upgrade a portion of an engine's primary fuel into a hydrogen-rich gas, thereby converting part of the exhaust heat from an internal combustion engine into chemical potential energy. Enriching the primary fuel air mixture of the internal combustion engine with this hydrogen-rich gas potentially enables combustion with very lean or dilute mixtures, resulting in higher efficiency and lower emissions as compared to standard combustion regimes. It may be possible to simplify thermochemical recuperation system architecture by directly mixing exhaust gases with the fuel in the reformation process to supply a significant portion of the heat and water required. To evaluate the effect of direct exhaust gas mixing on ethanol autothermal reformation, this work experimentally and theoretically investigated dilution with a mixture of nitrogen and carbon dioxide to simulate an exhaust composition, in combination with a range of inlet temperatures, to simulate exhaust gas temperatures, at a constant steam to carbon ratio. Parameters such as the chemical coefficient of performance, chemical energy output divided by chemical energy input, are introduced to better enable quantification of thermochemical recuperation. Trends in yield and performance metrics for ethanol autothermal reformation were observed under operating conditions across a range of oxygen to carbon ratio, a range of dilution amount, and a range of inlet temperature. For high inlet temperature cases, dilution increases hydrogen yield and chemical coefficient of performance suggesting that direct exhaust mixing would be beneficial. However, for low inlet temperatures, dilution decreased hydrogen yield and other performance metrics suggesting that direct exhaust mixing would not be beneficial. Dilution decreased methane production for many conditions. High inlet temperature conditions were found to cause homogeneous oxidation and homogenous conversion of ethanol upstream of the catalyst leading to high conversions of ethanol and high methane yields before reaching the catalyst. Coke formation rates varied over two orders of magnitude, with high coke formation rates for the high inlet temperature cases and low coke formation rates for the low inlet temperature cases. Dilution decreased the rate of coke formation. Models of intrinsic rate phenomenon were constructed in this study. The models predict that mass transport rates will be faster than the rate of chemical reaction kinetics over the range of ethanol concentrations and temperatures measured in the catalyst monolith both with and without dilution. Bounding cases for heat generation and transfer rates indicate that these phenomena could be the rate limiting mechanism or could be faster than both chemical kinetics and mass transport rates depending upon the distribution of oxidation heat between the catalyst and gas stream. Based on these results direct exhaust gas mixing is expected to be a practical method for supplying heat and water vapor for ethanol autothermal reformation in thermochemical recuperation systems when exhaust temperatures are above a certain threshold. For low exhaust temperatures direct exhaust gas mixing can supply water vapor but reduces other performance metrics.

Author : Eric Rogier
Publisher :
Page : 76 pages
File Size : 45,58 MB
Release : 2017
Category : Engineering design
ISBN :

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Solid Oxide Fuel Cells (SOFC) as the heat source for a heat engine power cycle can greatly increase the overall efficiency. The maximum efficiency is limited in at least the following ways. All thermal heat engine power cycles are limited by the Carnot efficiency which is a function of the hot and cold reservoirs the cycle operates between. Another irreversibility that limits the maximum efficiency of a fossil fuel cycle is the combustion reaction. In a boiler or combustion chamber, the chemical reaction of combustion happens spontaneously, meaning that the reaction happens without being used to generate power. A fuel cell decreases this irreversibility because it generates work as the combustion reaction happens. A SOFC can do this without an expensive catalyst due to the higher operating temperature. The power generated by the fuel cell can be added to the power generated by the thermal power cycle operating from the exhaust of the SOFC. The total work generated would be more than the system would have generated from just the heat engine resulting in a higher overall efficiency for the cycle. A SOFC and a recovery power cycle was simulated in Engineering Equation Solver (EES) to solve for ideal operating conditions. The fuel cell and gas turbine system had a net power output of 136 MW and had an efficiency of 60.84%, assuming the fuel cell had an 85% fuel utilization.

Author : Andrea Gil Arbues
Publisher :
Page : pages
File Size : 36,24 MB
Release : 2011
Category :
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Also in modern combustion engines, the maximal energetic efficiency is lower than 45%, which means that 55% of the supplied energy is lost and released to the environment. Automobile manufacturers and R&D partner suppliers are taking a special concern in investigating heat energy from exhaust gases, with the aim of recovering part of the heat by means of a Rankine Process and using it for energy cogeneration in the automobile. In the context of this Master Thesis, a new calculation software of the different thermodynamic states of the waste heat recovery system has to be programmed and used together with the rest of the available calculation tools. Another objective of this Master Thesis is the set up of valid simulation models for the different components of the heat recovery system based on measured testing data. This technical conditions and on the other hand the cycle requirements with the final objective of finding optimized states for each component. Finally, in order to reflect the behaviour of the system as a whole, the integration of the different simulated components of the waste heat recovery model would come in very useful. A complete simulation of the system would enable the estimation of optimization issues of the different parameters and operating points of the cycle.