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First published in 1979, this is a self-contained account of the theory of surface physics. In drawing together many results only previously reported in research papers, the authors emphasise basic disciplines such as electrodynamics and electron gas theory and demonstrate their application to simple models. Connections between intuitive derivations and more rigourous formulations are explained and there is an extensive treatment of the general problem of matching at a surface as a mathematical formalism with a physical meaning. Commonly recurring concepts such as surface modes, Green functions and phase shifts link different parts of the book, so giving coherence to the theory as a whole. A good background in physics is assumed but no previous acquaintance with surface physics. Starting from first principles, the reader is led from elementary analysis to the level of current research literature. The book is thus suitable for postgraduate students, post-doctoral workers or anyone wanting a systematic introduction to the field.
There is considerable interest, both fundamental and technological, in the way atoms and molecules interact with solid surfaces. Thus the description of heterogeneous catalysis and other surface reactions requires a detailed understand ing of molecule-surface interactions. The primary aim of this volume is to provide fairly broad coverage of atoms and molecules in interaction with a variety of solid surfaces at a level suitable for graduate students and research workers in condensed matter physics, chemical physics, and materials science. The book is intended for experimental workers with interests in basic theory and concepts and had its origins in a Spring College held at the International Centre for Theoretical Physics, Miramare, Trieste. Valuable background reading can be found in the graduate-Ievel introduction to the physics of solid surfaces by ZangwilI(1) and in the earlier works by Garcia Moliner and F1ores(2) and Somorjai.(3) For specifically molecule-surface interac tions, additional background can be found in Rhodin and Ertl(4) and March.(S) V. Bortolani N. H. March M. P. Tosi References 1. A. Zangwill, Physics at Surfaces, Cambridge University Press, Cambridge (1988). 2. F. Garcia-Moliner and F. Flores, Introduction to the Theory of Solid Surfaces, Cambridge University Press, Cambridge (1979). 3. G. A. Somorjai, Chemistry in Two Dimensions: Surfaces, Cornell University Press, Ithaca, New York (1981). 4. T. N. Rhodin and G. Erd, The Nature of the Surface Chemical Bond, North-Holland, Amsterdam (1979). 5. N. H. March, Chemical Bonds outside Metal Surfaces, Plenum Press, New York (1986).
Principles of Adsorption and Reaction on Solid Surfaces As with other books in the field, Principles of Adsorption and Reaction on Solid Surfaces describes what occurs when gases come in contact with various solid surfaces. But, unlike all the others, it also explains why. While the theory of surface reactions is still under active development, the approach Dr. Richard Masel takes in this book is to outline general principles derived from thermodynamics and reaction rate theory that can be applied to reactions on surfaces, and to indicate ways in which these principles may be applied. The book also provides a comprehensive treatment of the latest quantitative surface modeling techniques with numerous examples of their use in the fields of chemical engineering, physical chemistry, and materials science. A valuable working resource and an excellent graduate-level text, Principles of Adsorption and Reaction on Solid Surfaces provides readers with: * A detailed look at the latest advances in understanding and quantifying reactions on surfaces * In-depth reviews of all crucial background material * 40 solved examples illustrating how the methods apply to catalysis, physical vapor deposition, chemical vapor deposition, electrochemistry, and more * 340 problems and practice exercises * Sample computer programs * Universal plots of many key quantities * Detailed, class-tested derivations to help clarify key results The recent development of quantitative techniques for modeling surface reactions has led to a number of exciting breakthroughs in our understanding of what happens when gases come in contact with solid surfaces. While many books have appeared describing various experimental modeling techniques and the results obtained through their application, until now, there has been no single-volume reference devoted to the fundamental principles governing the processes observed. The first book to focus on governing principles rather than experimental techniques or specific results, Principles of Adsorption and Reaction on Solid Surfaces provides students and professionals with a quantitative treatment of the application of principles derived from the fields of thermodynamics and reaction rate theory to the investigation of gas adsorption and reaction on solid surfaces. Writing for a broad-based audience including, among others, chemical engineers, chemists, and materials scientists, Dr. Richard I. Masel deftly balances basic background in areas such as statistical mechanics and kinetics with more advanced applications in specialized areas. Principles of Adsorption and Reaction on Solid Surfaces was also designed to provide readers an opportunity to quickly familiarize themselves with all of the important quantitative surface modeling techniques now in use. To that end, the author has included all of the key equations involved as well as numerous real-world illustrations and solved examples that help to illustrate how the equations can be applied. He has also provided computer programs along with universal plots that make it easy for readers to apply results to their own problems with little computational effort. Principles of Adsorption and Reaction on Solid Surfaces is a valuable working resource for chemical engineers, physical chemists, and materials scientists, and an excellent text for graduate students in those disciplines.
This book emphasises both experimental and theoretical aspects of surface, interface and thin film physics. Compa- red to the earlier editions, which bore the title "Surfaces and Interfaces of Solid Materials", the book now places more emphasis on thin films, including also their superconducting and ferromagnetic properties. The present 4th edition thus presents techniques of preparing well-defined solid surfaces and interfaces, fundamental aspects of adsorption and layer growth, as well as basic models for the descripti- on of structural, vibronic and electronic properties of sur- faces, interfaces and thin films. Because of their importan- ce for modern information technology, significant attention is paid to the electronic properties of semiconductor inter- faces and heterostructures. Collective phenomena , such as superconductivity and ferromagnetism, also feature promi- nently. Experimental sections covering essential measurement and preparation techniques are presented in separate panels.
The theory of surface states underlies our knowledge of the behavior of electrons at solid surfaces, which is of paramount importance in understanding the mechanisms by which solid-state devices operate and catalytic reactions proceed. In this work, the subject is viewed through the "theoretical eye" of a physicist, but the topics are treated in an elementary fashion. The main features of the presentation are its instructive, model-based approach; detailed step-by-step derivations of the equations; smooth progression through the simple wave-function matching techniques to the more sophisticated Green-function methods; and the historical theme, which traces the evolution of the subject from its founding by the Nobel Laureate Igor Tamm in 1932, through the invention of the transistor in 1947 by Schockley, Bardeen and Brattain, to recent developments. The book will appeal to both theoretical and experimental surface scientists from chemistry, materials science, and electronic engineering.
While the standard solid state topics are covered, the basic ones often have more detailed derivations than is customary (with an empasis on crystalline solids). Several recent topics are introduced, as are some subjects normally included only in condensed matter physics. Lattice vibrations, electrons, interactions, and spin effects (mostly in magnetism) are discussed the most comprehensively. Many problems are included whose level is from "fill in the steps" to long and challenging, and the text is equipped with references and several comments about experiments with figures and tables.
Professor Ziman's classic textbook on the theory of solids was first pulished in 1964. This paperback edition is a reprint of the second edition, which was substantially revised and enlarged in 1972. The value and popularity of this textbook is well attested by reviewers' opinions and by the existence of several foreign language editions, including German, Italian, Spanish, Japanese, Polish and Russian. The book gives a clear exposition of the elements of the physics of perfect crystalline solids. In discussing the principles, the author aims to give students an appreciation of the conditions which are necessary for the appearance of the various phenomena. A self-contained mathematical account is given of the simplest model that will demonstrate each principle. A grounding in quantum mechanics and knowledge of elementary facts about solids is assumed. This is therefore a textbook for advanced undergraduates and is also appropriate for graduate courses.