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Excitations in Organic Solids

Author : Vladimir M. Agranovich
Publisher : OUP Oxford
Page : 512 pages
File Size : 43,96 MB
Release : 2009-02-12
Category : Science
ISBN : 0191552917

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During the last decade our expertise in nanotechnology has advanced considerably. The possibility of incorporating in the same nanostructure different organic and inorganic materials has opened up a promising field of research, and has greatly increased the interest in the study of properties of excitations in organic materials. In this book not only the fundamentals of Frenkel exciton and polariton theory are described, but also the electronic excitations and electronic energy transfers in quantum wells, quantum wires and quantum dots, at surfaces, at interfaces, in thin films, in multilayers, and in microcavities. Among the new topics in the book are those devoted to the optics of hybrid Frenkel-Wannier-Mott excitons in nanostructures, polaritons in organic microcavities including hybrid organic-inorganic microcavities, new concepts for organic light emitting devices, the mixing of Frenkel and charge-transfer excitons in organic quasi one-dimensional crystals, excitons and polaritons in one and two-dimensional crystals, surface electronic excitations, optical biphonons, and Fermi resonances by polaritons. All new phenomena described in the book are illustrated by available experimental observations. The book will be useful for scientists working in the field of photophysics and photochemistry of organic solids (for example, organic light-emitting devices and solar cells), and for students who are entering this field. It is partly based on a book by the author written in 1968 - "Theory of Excitons" - in Russian. However the new book includes only 5 chapters from this version, all of which have been updated. The 10 new chapters contain discussions of new phenomena, their theory and their experimental observations.

Electronic Excited States in Quasi- One- Dimensional Organic Solids with Strong Coupling of Frenkel and Charge-transfer Excitons

Author :
Publisher :
Page : pages
File Size : 45,85 MB
Release : 2002
Category :
ISBN :

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This work offers a concept to predict and comprehend the electronic excited states in regular aggregates formed of quasi-one-dimensional organic materials. The tight face-to-face stacking of the molecules justifies the idealization of the crystals and clusters as weakly interacting stacks with leading effects taking place within the columnar sub-structures. Thus, the concept of the small radius exciton theory in linear molecular chains was adopted to examine the excitonic states. The excited states are composed of molecular excitations and nearest neighbor charge transfer (CT) excitations. We analyzed the structure and properties of the excited states which result from the coupling of Frenkel and CT excitons of arbitrary strength in finite chains with idealized free ends. With the help of a partially analytical approach to determine the excitonic states of mixed Frenkel CT character by introducing a complex wave vector, two main types of states can be distinguished. The majority of states are bulk states with purely imaginary wavevector. The dispersion relation of these state matches exactly the dispersion relation known from the infinite chain. The internal structure of the excitons in infinite chains is directly transferred to the bulk states in finite chains. TAMM-like surface states belong to the second class of states. Owing to the damping mediated by a a non-vanishing real part of the wavevector, the wave function of the surface states is localized at the outermost molecules. The corresponding decay length is exclusively determined by the parameterization of the coupling and is independent of the system size. It can therefore be assigned as a characteristic quantum length which plays a vital role for the understanding of system-dependent behavior of the states. The number and type of surface states occurring is predicted for any arbitrary coupling situation. The different nature of bulk and surface states leads to distinct quantum confinement effects. Two regi.

Organic Molecular Solids

Author : Markus Schwoerer
Publisher : John Wiley & Sons
Page : 451 pages
File Size : 33,41 MB
Release : 2007-04-09
Category : Science
ISBN : 3527405402

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This is the first comprehensive textbook on the physical aspects of organic solids. All phenomena which are necessary in order to understand modern technical applications are being dealt with in a way which makes the concepts of the topics accessible for students. The chapters - from the basics, production and characterization of organic solids and layers to organic semiconductors, superconductors and opto-electronical applications - have been arranged in a logical and well thought-out order.

Electronic Excitations in Organic Based Nanostructures

Author :
Publisher : Elsevier
Page : 509 pages
File Size : 17,8 MB
Release : 2003-11-13
Category : Technology & Engineering
ISBN : 0080519210

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The first book devoted to a systematic consideration of electronic excitations and electronic energy transfer in organic crystalline multilayers and organics based nanostructures(quantum wells, quantum wires, quantum dots, microcavities). The ingenious combination of organic with inorganic materials in one and the same hybrid structure is shown to give qualitatively new opto-electronic phenomena, potentially important for applications in nonlinear optics, light emitting devices, photovoltaic cells, lasers and so on. The book will be useful not only for physicists but also for chemists and biologists.To help the nonspecialist reader, three Chapters which contain a tutorial and updated introduction to the physics of electronic excitations in organic and inorganic solids have been included. * hybrid Frenkel-Wannier-Mott excitons * microcavities with crystalline and disordered organics * electronic excitation at donor-acceptor interfaces * cold photoconductivity at donor-acceptor interface * cummulative photovoltage * Feorster transfer energy in microcavity * New concepts for LEDs

Organic Optoelectronics

Author : Wenping Hu
Publisher : John Wiley & Sons
Page : 503 pages
File Size : 45,37 MB
Release : 2012-11-05
Category : Technology & Engineering
ISBN : 3527653473

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Written by internationally recognized experts in the field with academic as well as industrial experience, this book concisely yet systematically covers all aspects of the topic. The monograph focuses on the optoelectronic behavior of organic solids and their application in new optoelectronic devices. It covers organic field-effect and organic electroluminescent materials and devices, organic photonics, materials and devices, as well as organic solids in photo absorption and energy conversion. Much emphasis is laid on the preparation of functional materials and the fabrication of devices, from materials synthesis and purification, to physicochemical properties and the basic processes and working principles of the devices. The only book to cover fundamentals, applications, and the latest research results, this is a handy reference for both researchers and those new to the field. From the contents: * Electronic process in organic solids * Organic/polymeric semiconductors for field-effect transistors * Organic/polymeric field-effect transistors * Organic circuits and organic single molecular transistors * Polymer light-emitting Diodes (PLEDs): devices and materials * Organic solids for photonics * Organic photonic devices * Organic solar cells based on small molecules * Polymer solar cells * Dye-sensitized solar cells (DSSCs) * Organic thermoelectric power devices

Organic Molecular Solids

Author : Markus Schwoerer
Publisher : John Wiley & Sons
Page : 438 pages
File Size : 34,91 MB
Release : 2008-09-26
Category : Science
ISBN : 352761866X

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This is the first comprehensive textbook on the physical aspects of organic solids. All phenomena which are necessary in order to understand modern technical applications are being dealt with in a way which makes the concepts of the topics accessible for students. The chapters - from the basics, production and characterization of organic solids and layers to organic semiconductors, superconductors and opto-electronical applications - have been arranged in a logical and well thought-out order.

Spectroscopy and Dynamics of Collective Excitations in Solids

Author : Baldassare di Bartolo
Publisher : Springer Science & Business Media
Page : 678 pages
File Size : 20,50 MB
Release : 2012-12-06
Category : Science
ISBN : 1461558352

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This book presents the proceedings of the course "Spectroscopy and Dynamics of Collective Excitations in Solids" held in Erice, Italy from June 17 to July 1, 1995. This meeting was organized by the International School of Atomic and Molecular Spectroscopy of the "Ettore Majorana" Centre for Scientific Culture. The purpose of this course was to present and discuss physical models, mathematical formalisms, experimental techniques and applications relevant to the subject of collective excitations in solids. By bringing together specialists in the field of solid state spectroscopy, this course provided a much needed forum for the critical assessment and evaluation of recent and past developments in the physics of solids. A total of 83 participants came from 57 laboratories and 20 different countries (Austria, Belgium, Brazil, Denmark, Finland, France, Germany, Greece, Israel, Italy, Japan, The Netherlands, Norway, Portugal, Russia, Spain, Switzerland, Turkey, the United Kingdom, and the United States). The secretaries of the course were Stamatios K yrkos and Daniel Di Bartolo. 45 lectures divided in 13 series were given. In addition 8 (one or two-hour) "long seminars," 1 "special lecture," 2 interdisciplinary lectures, 29 "short seminars," and 16 posters were presented. The sequence of lectures was in accordance with the logical development of the subject of the meeting. Each lecturer started at a rather fundamental level and ultimately reached the frontier of knowledge in the field.

Elementary Excitations In Solids

Author : David Pines
Publisher : CRC Press
Page : 235 pages
File Size : 37,98 MB
Release : 2018-03-05
Category : Science
ISBN : 0429980485

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This text continues to fill the need to communicate the present view of a solid as a system of interacting particles which, under suitable circumstances, behaves like a collection of nearly independent elementary excitations. In addition to introducing basic concepts, the author frequently refers to experimental data. Usually, both the basic theory and the applications discussed deal with the behavior of '`'simple' metals, rather than the '`'complicated' metals, such as the transition metals and the rare earths. Problems have been included for most of the chapters.

Electrical and Related Properties of Organic Solids

Author : R.W. Munn
Publisher : Springer Science & Business Media
Page : 442 pages
File Size : 50,74 MB
Release : 2012-12-06
Category : Technology & Engineering
ISBN : 9401157901

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Organic solids exhibit a wide range of electrical and related properties. They occur as crystals, glasses, polymers and thin films; they may be insulators, semiconductors, conductors or superconductors; and they may show luminescence, nonlinear optical response, and complex dynamical behaviour. The book provides a broad survey of this area, written by international experts, one third being drawn from Eastern Europe. Electrical, optical, spectroscopic and structural aspects are all treated in a way that gives an excellent introduction to current themes in this highly interdisciplinary and practically important area. The coverage is especially strong in the areas where electrical and optical properties overlap, such as photoconductivity, electroluminescence, electroabsorption, electro-optics and photorefraction.