Author : Georgii G. Furin
Publisher : CLEUP
Page : 212 pages
File Size : 47,78 MB
Release : 1996
Category : Science
ISBN : 9788871783956
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Direct Fluorination of Organic Compounds
Author : John L. Margrave
Publisher :
Page : 38 pages
File Size : 40,6 MB
Release : 1972
Category :
ISBN :
The synthesis of perfluoro organic compounds by direct fluorination has been studied. The compounds studied included: ortho-toluic acid, meta-toluic acid, para-toluic acid, sodium acetate, diglycolic acid, diphenyl ether, 2- ethoxyethylacetate, 3-oxoglutaric acid, 2-oxoglutaric acid, methoxyasetic acid, methoxyphenoxyacetic acid, diethyl carbonate, malonic acid, adipic acid. These materials have been fluorinated at low concentrations of fluorine and at a variety of temperatures varying from room temperature to -78C. Invariably with extremely low fluorine con-centrations, the resulting products contained very little fluorinated material as evidenced by their infrared spectra. Under longer reaction times and/or higher fluorine concentrations, the materials tended to be degraded into low molecular weight volatiles. Polyethylene has been surface fluorinated and the kinetics of the process have been studied from 25 to 50 C. The rate of constants for each temperature and the activation energy of the process are reported. Natural rubber samples were surface treated with fluorine and appear to survive acceptably with a subsequent lowering of surface energy. Matrix isolation studies of organic molecules in fluorine matrices are also reported. The species studied were methane, ethane, ethylene, acetylene, and formic acid. It was found that fluorine molecules at 4-15 K behaved essentially like an inert substrate, but fluorine atoms, prepared in situ by photolysis, are very reactive and lead to various fluorinated derivatives.
Direct Fluorination of Inorganic and Organic Compounds
Author : Norma Jean Maraschin
Publisher :
Page : 266 pages
File Size : 47,22 MB
Release : 1974
Category :
ISBN :
Direct fluorination of organic compounds
Author : Wayne D. Clark
Publisher :
Page : 372 pages
File Size : 23,22 MB
Release : 1989
Category : Fluorination
ISBN :
Synthesis of novel fluorinated organic compounds by direct fluorination
Author : Hsu-Nan Huang
Publisher :
Page : 330 pages
File Size : 47,35 MB
Release : 1986
Category : Organic compounds
ISBN :
The Action of Elementary Fluorine Upon Organic Compounds
Author : John Anthony Cuculo
Publisher :
Page : 713 pages
File Size : 48,96 MB
Release : 1952
Category : Acetonitrile
ISBN :
The Action of Elementary Fluorine Upon Organic Compounds. XXVI.
Author : John Barry Hynes
Publisher :
Page : 86 pages
File Size : 45,93 MB
Release : 1963
Category :
ISBN :
Synthetic Aspects of the Fluorination of Organic Compounds
Author : G. G. Furin
Publisher : Taylor & Francis US
Page : 158 pages
File Size : 44,10 MB
Release : 1991
Category : Science
ISBN : 9783718651573
The Action of Elementary Fluorine Upon Organic Compounds. XXV.
Author : John Barry Hynes
Publisher :
Page : 2755 pages
File Size : 44,70 MB
Release : 1962
Category :
ISBN :
The Separation and Identification of Some New Highly Fluorinated Organic Compounds of Nitrogen Prepared by Direct Fluorination ...
Author : John Barry Hynes
Publisher :
Page : 278 pages
File Size : 12,33 MB
Release : 1961
Category : Organofluorine compounds
ISBN :