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Author : Daniel J. Hall
Publisher :
Page : 0 pages
File Size : 47,13 MB
Release : 2008
Category :
ISBN :
Author : Krzysztof Matyjaszewski
Publisher : Academic
Page : 444 pages
File Size : 24,20 MB
Release : 2009
Category : Language Arts & Disciplines
ISBN :
Recent progress in the field of controlled/living radical polymerization.
Author : Mustafa Çıkılmazkaya
Publisher :
Page : pages
File Size : 13,19 MB
Release : 2003
Category :
ISBN :
Author : Graeme Moad
Publisher : Elsevier
Page : 667 pages
File Size : 44,67 MB
Release : 2006
Category : Science
ISBN : 0080442889
This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.
Author : Munmaya Mishra
Publisher : CRC Press
Page : 784 pages
File Size : 28,92 MB
Release : 2008-07-24
Category : Technology & Engineering
ISBN : 0824725956
Radical polymerization is one of the most widely used means of producing vinyl polymers, supporting a myriad of commercial uses. Maintaining the quality of the critically acclaimed first edition, the Handbook of Vinyl Polymers: Radical Polymerization, Process, and Technology, Second Edition provides a fully updated, single-volume source on the chemistry, technology, and applications of vinyl polymers. Emphasizes radical initiating systems and mechanisms of action... Written by renowned researchers in the field, this handbook is primarily concerned with the physical and organic chemistry of radical vinyl polymerization. The authors survey the most recent advances, processing methods, technologies, and applications of free radical vinyl polymerization. The book features thorough coverage of polymer functionalization, photo initiation, block and graft copolymers, and polymer composites. Analyzes living/controlled radical polymerization, one of the latest developments in the field... Combining fundamental aspects with the latest advances, processing methods, and applications in free radical vinyl polymerization and polymer technology, this invaluable reference provides a unified, in-depth, and innovative perspective of radical vinyl polymerization.
Author :
Publisher :
Page : 428 pages
File Size : 17,65 MB
Release : 2015
Category :
ISBN :
Reversible deactivation radical polymerization (RDRP), also known as controlled radical polymerization (CRP), has been a significant area of polymer research for more than 20 years, allowing the facile synthesis of complex macromolecules previously unattainable by conventional free radical polymerization (FRP). However, industrial adoption of RDRP has been minimal largely due to the significant economic barrier to commercialization, with complex synthesis of the mediating agents required and the necessary post polymerization processing to recover the mediating agent. In an effort to overcome this obstacle to industrial adoption, the mediating agent concentration can be significantly reduced, such as the copper level in activator regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP), or the mediating agent can be incorporated into the polymer as in nitroxide-mediated polymerization (NMP), where no post polymerization processing is required other than removal of residual monomer. This thesis presents a study of these two chemistries towards industrially relevant conditions. To build upon recent developments of continuous ARGET ATRP, a systematic batch study is conducted to pursue decreased copper levels in the generation of short chain acrylic and methacrylic polymers of interest to the coatings industry. The limitations to reducing copper levels are understood with the development of a kinetic model, with the improved understanding of the ARGET ATRP system suggesting that a reduction in copper loading must be accompanied by an increase in reducing agent loading in order to maintain an appreciable polymerization rate. Alternatively, NMP does not require a reduction in mediating nitroxide level as it reversibly terminates the polymer chain end, and may present a smaller barrier to commercialization. Indeed, certain nitroxides are currently produced at pilot scale. However, limited research has been conducted into continuous operation which is commonly used in industry to improve productivity. A batch NMP study at elevated temperatures demonstrates the effectiveness of a novel alkoxyamine to mediate the polymerization of styrene and butyl acrylate under industrially relevant conditions. A kinetic study is developed to understand the novel system, and the polymerization is implemented in a continuous stirred-tank reactor (CSTR), the first demonstration of NMP in an existing industrial process.
Author : Krzysztof Matyjaszewski
Publisher : John Wiley & Sons
Page : 934 pages
File Size : 34,4 MB
Release : 2003-04-14
Category : Technology & Engineering
ISBN : 0471461571
Klassische und moderne Verfahren der radikalischen Polymerisation: In diesem handlichen Band finden Sie Antworten auf theoretische und praktische Fragen. Neben grundlegenden Ausführungen zur Einteilung radikalischer Polymere sind Angaben über die wichtigsten experimentellen Verfahren zur Synthese, Reinigung und Charakterisierung von Polymeren enthalten. Interessante Zugabe: ein Abriß der Geschichte der Radikalkettenpolymerisation.
Author : Christopher Barner-Kowollik
Publisher : John Wiley & Sons
Page : 556 pages
File Size : 28,21 MB
Release : 2008-09-08
Category : Technology & Engineering
ISBN : 3527622764
Spanning the entire field from fundamentals to applications in material science, this one-stop source is the first comprehensive reference for polymer, physical and surface chemists, materials scientists, chemical engineers, and those chemists working in industry. From the contents: * Introduction: Living Free Radical Polymerization and the RAFT Process * Fundamental Structure-Reactivity Correlations Governing the RAFT Process * Mechanism and Kinetics * The RAFT Process as a Kinetic Tool * Theory and Practice in Technical Applications * RAFT Polymerization in Bulk and Organic Solvents, as well as Homogeneous Aqueous Systems * Emulsion and Mini-Emulsion Polymerization * Complex Architecture Design * Macromolecular Design via the Interchange of Xanthates * Surface Modification * Stability and Physical Properties of RAFT Polymers * Novel Materials: From Drug Delivery to Opto-Electronics * Outlook and Future Developments
Author : Akihiro Abe
Publisher : Springer
Page : 253 pages
File Size : 22,83 MB
Release : 2014-07-08
Category : Technology & Engineering
ISBN : 3319029193
Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.
Author : Jean-François Lutz
Publisher : John Wiley & Sons
Page : 532 pages
File Size : 44,10 MB
Release : 2018-04-09
Category : Technology & Engineering
ISBN : 3527342370
Edited by a leading authority in the field, the first book on this important and emerging topic provides an overview of the latest trends in sequence-controlled polymers. Following a brief introduction, the book goes on to discuss various synthetic approaches to sequence-controlled polymers, including template polymerization, genetic engineering and solid-phase chemistry. Moreover, monomer sequence regulation in classical polymerization techniques such as step-growth polymerization, living ionic polymerizations and controlled radical polymerizations are explained, before concluding with a look at the future for sequence-controlled polymers. With its unique coverage of this interdisciplinary field, the text will prove invaluable to polymer and environmental chemists, as well as biochemists and bioengineers.