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This series presents critical reviews of the present position and future trends in modern chemical research. The short and concise reports on chemistry are each written by world renowned experts. This series is still valid and useful after 5 or 10 years. More information as well as the electronic version of the whole content available at: springerlink.com.
This series presents critical reviews of the present position and future trends in modern chemical research. The short and concise reports on chemistry are each written by world renowned experts. This series is still valid and useful after 5 or 10 years. More information as well as the electronic version of the whole content available at: springerlink.com.
normal and pathological mineralization in vertebrates but also with the interesting problems involved in the formation of in tracellular deposits of calcium oxalate in plants. Here cal cium carbonate and silica may also be involved in the mineral ization processes. Calcium carbonate is an important component in the formation of mollusc and avian shells. The observation that both calcite and aragonite may be formed in biogenic cal cium carbonate raises important questions as to what factors control the formation of the final mineral phase. There is little doubt that thermodynamically less stable phases may be kinetically stabilized for long periods of time by other mole cules present in vivo. In normal mineralization, calcium salts may initially be deposited both within the cells and extracel lularly. In the latter case, the role of matrix vesicles and the ways in which the matrix components might control mineral ization were especially emphasized. There is clearly a need for more structural and functional information involving cells, matrix components, and their associated crystals. The develop ment of further techniques involving mutants, chromofluors, and fixatives for preservation of tissue and the ions present in vivo was recommended. In dealing with abnormal and pathological mineralization, the Workshop concentrated on urolithiasis, gout and pseudo-gout, and the formation of dental caries. Discussions based on the influence of media of low pH on mineral surfaces highlighted some of the factors of importance in controlling crystal dis solution.
Biomineralization is a hot topic in the area of materials, and this volume in the Metals Ions in Life Sciences series takes a systematic approach, dealing with all aspects from the fundamentals to applications. Key biological features of biomineralization, such as gene directed growth and the role of enzymes are covered, as are new areas, including copper/zinc in the jaws of invertebrates or magnetic biomaterials that help birds with navigation
Teeth, bones, kidney stones, and skeletons of algae, mussels, and grasses: all examples of biomineralization. Whole mountains owe their existence to the ability of organisms to mineralize in their cells inorganic compounds from solutions. Those minerals made by organisms are used for various purposes. Some of these minerals are magnetic and therefore of interest to nanotechnology. Thus there is a rapidly growing number of research groups and journals worldwide dealing with biomineralization. This book provides a much-needed up-to-date account of the important developments in biomineralization, focusing on investigations of unicellular organisms. An international and interdisciplinary team of authors, under the direction of a leading expert in the field, presents research results from first-hand experience as well as general information and a full list of references. Specific applications, such as the use of biominerals as contrast agents in cancer therapy, the templated crystallization of colloids, and in nanotechnology are highlights of this book.
Biominerals are generated by the subtle interaction of biological organization and mineral growth. They belong both to the living and the inanimate world and as such their genesis is among the most intri guing and fundamental subjects in science. However, the conceptual and technical resources that are available in physical chemistry and in the biological sciences is often inadequate for the elucidation of the pro blems involved, and hence this field is particularly difficult to ex plore. This may be an important reason why fundamental research on bio mineralization mechanisms has traditionally been carried out by a com paratively small group of scientists. There are signs, however, that the situation is ripe for a change. Various meetings on biomineralization have been organized in the last few years, particularly in the medical sector. It is generally felt that further developments in the therapy of bone and tooth diseases will be largely dependent on an improved understanding of the fundamen tal underlying mechanisms of biomineralization.
What does it mean to be at the forefront of a characterization technique? Novel implementation and research, finding new ways to visualize composites, and new techniques all play a role. Yet with the myriad of advances in the field, keeping up with new and advanced techniques, often from many different areas, has become a challenge. Biomineralization Sourcebook: Characterization of Biominerals and Biomimetic Materials emphasizes the interplay between multiple techniques at their current frontiers and explores how such studies may be carried out. The book addresses atomic and molecular structure: how it is described, detected, and assessed for importance. It then highlights additional measurements especially well-suited to looking at two- and three-dimensional systems with heterogeneous, if not hierarchical, structure. These systems enable particular aspects of biominerals and biomimetic models to be scrutinized. The text presents state-of-the-art methods to assess properties of the composite, and represents current approaches and aspirations to measuring entire biological working structures while retaining as much fine-grained biophysical information as possible. In all these chapters, authors showcase discoveries from their own programs. Along the way, the book takes you on a tour from microscopy's eighteenth century roots, to the recent literature and diverse research programs of the contributing investigators, to the multi-million dollar National Laboratory facilities that all play their roles to illuminate the ever-fascinating biominerals. A snapshot of the state of the art in a spectrum of experimental techniques applied to a common interdisciplinary goal, where the ability to use the more advanced techniques often requires funding for collaboration and travel, the book will deepen the appreciation for the massive interdisciplinary effort underway, educate researchers across the field, and motivate new collaborations.
The importance of metals in biology, the environment and medicine has become increasingly evident over the last twenty five years. The study of the multiple roles of metal ions in biological systems, the rapidly expanding interface between inorganic chemistry and biology constitutes the subject called Biological Inorganic Chemistry. The present text, written by a biochemist, with a long career experience in the field (particularly iron and copper) presents an introduction to this exciting and dynamic field. The book begins with introductory chapters, which together constitute an overview of the concepts, both chemical and biological, which are required to equip the reader for the detailed analysis which follows. Pathways of metal assimilation, storage and transport, as well as metal homeostasis are dealt with next. Thereafter, individual chapters discuss the roles of sodium and potassium, magnesium, calcium, zinc, iron, copper, nickel and cobalt, manganese, and finally molybdenum, vanadium, tungsten and chromium. The final three chapters provide a tantalising view of the roles of metals in brain function, biomineralization and a brief illustration of their importance in both medicine and the environment. Relaxed and agreeable writing style. The reader will not only fiind the book easy to read, the fascinating anecdotes and footnotes will give him pegs to hang important ideas on.Written by a biochemist. Will enable the reader to more readily grasp the biological and clinical relevance of the subject.Many colour illustrations. Enables easier visualization of molecular mechanismsWritten by a single author. Ensures homgeneity of style and effective cross referencing between chapters
This new volume of Methods in Enzymology continues the legacy of this premier serial with quality chapters authored by leaders in the field. This volume covers research methods in biomineralization science, and includes sections on such topics as determining solution chemistry, structure and nucleation; probing structure and dynamics at surfaces; and interfaces mapping biomineral and morphology and ultrastructure. Continues the legacy of this premier serial with quality chapters authored by leaders in the field Covers research methods in biomineralization science Contains sections on such topics as and includes sections on such topics as determining solution chemistry, structure and nucleation; probing structure and dynamics at surfaces; and interfaces mapping biomineral and morphology and ultrastructure