Author : Anna Candace Badaj
Publisher :
Page : pages
File Size : 19,77 MB
Release : 2014
Category :
ISBN :
[PDF] Aryl Substituted Imino N Heterocyclic Carbene Complexes Of Late Transition Metals eBook
Aryl Substituted Imino N Heterocyclic Carbene Complexes Of Late Transition Metals Book in PDF, ePub and Kindle version is available to download in english. Read online anytime anywhere directly from your device. Click on the download button below to get a free pdf file of Aryl Substituted Imino N Heterocyclic Carbene Complexes Of Late Transition Metals book. This book definitely worth reading, it is an incredibly well-written.
Transition Metal Complexes of N-heterocyclic Carbenes and Derivatives Thereof
Author : Timothy Gordon Larocque
Publisher :
Page : pages
File Size : 13,27 MB
Release : 2013
Category :
ISBN :
N-heterocyclic carbenes (NHCs) have played a dominant role in organometallic chemistry for decades and revolutionized the field of homogenous catalysis. NHCs have been thoroughly studied, both experimentally and theoretically, and have shown unique reactivity towards transition metals, chalcogens, azides and pnictogens. This thesis is aimed at utilizing the unique reactivity of N-heterocyclic carbenes to develop novel, robust catalysts to mediate organic transformations. The multi-faceted work within this thesis explores the use of NHCs as ancillary ligands on early and late transition metals as potential catalysts for olefin polymerization and ring-closing metathesis, respectively. This work also includes exploring the synthesis and coordination of ancillary ligands derived from the unique reactivity of NHCs towards azides, chalcogens and pnictinidenes. The reactivity of a novel aryl-substituted acyclic imino-N-heterocyclic carbene to early transition metals, cyclooctasulfur and Grubbs-type ruthenium benzylidene complexes was explored. The reactivity of imidazol-2-imide towards Grubbs-type ruthenium benzylidene complexes and the synthesis and coordination of a novel group of ligands bearing an imidazol-2-imine scaffold were also explored. Lastly, this work will include the reactivity of IMes=PPh to Grubbs-type ruthenium benzylidene complexes.
Expanded Ring N-heterocyclic Carbene Complexes of the Late Transition Metals
Author : Jay James Dunsford
Publisher :
Page : 496 pages
File Size : 22,54 MB
Release : 2012
Category :
ISBN :
Transition Metal Complexes of Neutral eta1-Carbon Ligands
Author : Remi Chauvin
Publisher : Springer
Page : 260 pages
File Size : 10,44 MB
Release : 2009-12-18
Category : Science
ISBN : 364204722X
Contents: Yves Canac and Remi Chauvin: Neutral eta1-carbon ligands: beyond carbon monoxide; Esteban P. Urriolabeitia: Ylide Ligands; Wolfgang Petz and Gernot Frenking: Carbodiphosphoranes and related ligands; Mareike C. Jahnke and F. Ekkehardt Hahn: Chemistry of N-Heterocyclic Carbene Ligands; Tsuyoshi Kato, Eddy Maerten, Antoine Baceiredo: Non-NHCs stable singlet carbene ligands; Victorio Cadierno, Sergio E. García-Garrido: All-Carbon-Substituted Allenylidene and Related Cumulenylidene Ligands; Victorio Cadierno, Sergio E. García-Garrido: Heteroatom-Conjugated Allenylidene and Related Cumulenylidene Ligands.
Synthesis, Characterization and Reactivity Study of Bis (Imino)-N-Heterocyclic Carbene Transition Metal Complexes
Author : Jameel Raddah Al-Thagfi
Publisher :
Page : pages
File Size : 35,99 MB
Release : 2014
Category :
ISBN :
Synthesis and Characterisation of Late Transition Metal Complexes Containing Novel Mixed N-heterocyclic Carbene and Thione Donors
Author :
Publisher :
Page : 122 pages
File Size : 16,70 MB
Release : 2012
Category :
ISBN :
Mechanistic Insights Into Late Transition Metal-Catalyzed Olefin Hydrosilylation and Synthesis of New N-Heterocyclic Carbene and Dinuclear Complexes
Author : Korbinian Riener
Publisher :
Page : pages
File Size : 50,35 MB
Release : 2016
Category :
ISBN : 9783843926225
Synthesis of Unsymmetrically Substituted Free N-heterocyclic Carbenes, Electron Rich Olefines and Their Transition Metal Complexes
Author : María Dolores Ibarra Arias
Publisher :
Page : 142 pages
File Size : 48,84 MB
Release : 2007
Category :
ISBN :
N-heterocyclic carbenes of late transition metals in catalysis
Author : Li Min Serena Goh
Publisher :
Page : 161 pages
File Size : 12,90 MB
Release : 2012
Category :
ISBN : 9783843904919
Late Transition Metal-Carboryne Complexes
Author : Zaozao Qiu
Publisher : Springer Science & Business Media
Page : 143 pages
File Size : 22,75 MB
Release : 2012-01-05
Category : Science
ISBN : 3642243614
Zaozao Qiu shows in this thesis that transition metals can mediate or catalyze the cycloaddition or coupling reactions of carboryne with alkynes or alkenes to afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes. These results represent powerful strategies to assemble useful complex molecules from very simple precursors in a single operation. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and the limited efficient synthetic methods to obtain functional carborane materials have restricted applications of carboranes within a narrow scope. This work breaks a new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.