[PDF] Advances In The Development And Application Of Deep Eutectic Solvents eBook

Author : Maria Luisa Di Gioia
Publisher : Frontiers Media SA
Page : 113 pages
File Size : 11,93 MB
Release : 2024-02-09
Category : Science
ISBN : 283254455X

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The continuous effort to perform a more sustainable chemistry has led to the development of new materials that accomplish the principles of green chemistry. In this context, deep eutectic solvents (DESs) have arisen as a new generation of solvents that respond well to most of the characteristics that an ideal green solvent must possess: they are easy and cheap to prepare, stable, easy to handle (they show chemical stability, non-flammability and conductivity), separable from the reaction products, biodegradable and safe for both humans and the environment. At the same time, they show chemical-physical properties similar to ionic liquids, such as low volatility, conductivity and high solvent power. These characteristics mean that DESs are today classified as 2-st century solvents. DESs have been raising a lot of attention and a sharp increase of their applications in numerous sectors of chemistry: they are mainly used as alternative solvents and/or catalysts for various organic transformations including metal-catalyzed reactions, biotransformations, polymerization, in sample preparation and analytical techniques as well as in the design of pharmaceutical formulations and drug delivery systems.

Author : Ashish Pandey
Publisher : Elsevier
Page : 446 pages
File Size : 38,13 MB
Release : 2022-09-10
Category : Technology & Engineering
ISBN : 0323999565

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Deep eutectic solvents represent the newest addition among all other non-conventional and alternate solvent systems. Deep Eutectic Solvent Fund Emerging Applications provides detailed insights on these neoteric solvents, their synthesis methods, types, physicochemical properties, and sustainable applications in emerging scientific areas. The book follows a mechanistic approach on understanding the role of DESs as sustainable media for CO2 capture, biomass pretreatment, as catalysts, as reaction media for material synthesis, cross coupling reactions, templates for drug delivery, etc. The book offers a springboard for encouraging vital discussions and inspiring further innovations in the field of environmentally benign eutectic solvent systems. Provides a detailed account of development on DESs with special focus on hydrophilic /hydrophobic DESs Describes experimental and theoretical outlook on the physical and chemical properties of DESs Discusses the toxicity profiling of DESs and their importance in designing biocatalytic routes Includes DESs in emerging areas - pharmaceuticals, drug discovery, functional materials and membrane science Covers use of DESs in CO2 capture, biomass transformations, organic reactions, etc.

Author : Diego J. Ramón
Publisher : John Wiley & Sons
Page : 384 pages
File Size : 19,58 MB
Release : 2020-01-13
Category : Science
ISBN : 3527345183

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A useful guide to the fundamentals and applications of deep eutectic solvents Deep Eutectic Solvents contains a comprehensive review of the use of deep eutectic solvents (DESs) as an environmentally benign alternative reaction media for chemical transformations and processes. The contributors cover a range of topics including synthesis, structure, properties, toxicity and biodegradability of DESs. The book also explores myriad applications in various disciplines, such as organic synthesis and (bio)catalysis, electrochemistry, extraction, analytical chemistry, polymerizations, (nano)materials preparation, biomass processing, and gas adsorption. The book is aimed at organic chemists, catalytic chemists, pharmaceutical chemists, biochemists, electrochemists, and others involved in the design of eco-friendly reactions and processes. This important book: -Explores the promise of DESs as an environmentally benign alternative to hazardous organic solvents -Covers the synthesis, structure, properties (incl. toxicity) as well as a wide range of applications -Offers a springboard for stimulating critical discussion and encouraging further advances in the field Deep Eutectic Solvents is an interdisciplinary resource for researchers in academia and industry interested in the many uses of DESs as an environmentally benign alternative reaction media.

Author : Justyna Płotka-Wasylka
Publisher : Springer
Page : 449 pages
File Size : 49,42 MB
Release : 2019-08-02
Category : Science
ISBN : 981139105X

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The book explains the principles and fundamentals of Green Analytical Chemistry (GAC) and highlights the current developments and future potential of the analytical green chemistry-oriented applications of various solutions. The book consists of sixteen chapters, including the history and milestones of GAC; issues related to teaching of green analytical chemistry and greening the university laboratories; evaluation of impact of analytical activities on the environmental and human health, direct techniques of detection, identification and determination of trace constituents; new achievements in the field of extraction of trace analytes from samples characterized by complex composition of the matrix; “green” nature of the derivatization process in analytical chemistry; passive techniques of sampling of analytes; green sorption materials used in analytical procedures; new types of solvents in the field of analytical chemistry. In addition green chromatography and related techniques, fast tests for assessment of the wide spectrum of pollutants in the different types of the medium, remote monitoring of environmental pollutants, qualitative and comparative evaluation, quantitative assessment, and future trends and perspectives are discussed. This book appeals to a wide readership of the academic and industrial researchers. In addition, it can be used in the classroom for undergraduate and graduate Ph.D. students focusing on elaboration of new analytical procedures for organic and inorganic compounds determination in different kinds of samples characterized by complex matrices composition.Jacek Namieśnik was a Professor at the Department of Analytical Chemistry, Gdańsk University of Technology, Poland. Justyna Płotka-Wasylka is a teacher and researcher at the same department.

Author : Matteo Tiecco
Publisher : Mdpi AG
Page : 104 pages
File Size : 27,99 MB
Release : 2022-03-25
Category : Science
ISBN : 9783036535630

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This reprint reports advances in the topic of Deep Eutectic Solvents regarding their use as green alternatives in different chemical applications. Studies on the extraction/preconcentration processes of pharmacologically relevant molecules, structural spectroscopic studies, and application in gas purification studies are reported. Two relevant reviews are also published in the context of carbon dioxide conversion and their use in the chemistry of transformations. This reprint therefore aims to summarize some of the pertinent issues in DES chemistry through relevant literature references.

Author :
Publisher : Academic Press
Page : 438 pages
File Size : 50,17 MB
Release : 2021-01-14
Category : Science
ISBN : 012821693X

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Eutectic Solvents and Stress in Plants, Volume 97 in the Advances in Botanical Research series, highlights new advances in the field, with this new volume presenting interesting chapters surrounding NADES: from simple systems to complex colloidal mixtures, DES nanostructures with water, micelle and DES interaction, Dissolving proteins protein physics, Enzyme reactions in NADES, Protection against oxidation of metabolites, stability food, DES for pharmaceutical preparations, Cosmetics, Metabolons and bio-condensates: the essence of plant plasticity and the key elements in development of green production systems, Immediate in the whole plant during extreme conditions metabolomics, NADES in sees spores, and much more. Provides the authority and expertise of leading contributors from an international board of authors Presents the latest release in the Advances in Botanical Research series Updated release includes the latest information on Eutectic Solvents and Stress in Plants

Author : Pratima Bajpai
Publisher : Springer Nature
Page : 98 pages
File Size : 50,39 MB
Release : 2021-08-20
Category : Science
ISBN : 9811640130

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This book focuses on the properties of deep eutectic solvents (DESs) and recent advances in their application in lignocellulosic biomass processing. Lignocellulosic biomass conversion to biofuels, biochemicals and other value-added products has attracted global attention because it is a readily available, inexpensive and renewable resource. However, in order for biomass technologies to be commercially viable, biomass recalcitrance needs to be cost-effectively reduced. Deep eutectic solvents (DESs) are new ‘green' solvents that have the high potential for biomass processing thanks to their low cost, low toxicity, biodegradability, and easy recycling and reuse. After an overview of the current lignocellulosic biomass pretreatment, the book discusses the synthesis and physiochemical properties of DESs, as well as key findings on the effects of DES on cellulose, hemicellulose and lignin solubilization, biomass pretreatment and biomass crystallinity. It then addresses the enzymatic hydrolysis performance of DES-pretreated solids, compatibility of DESs with enzymes and microorganisms, and the recycling potential of DESs. Lastly, it compares DESs with ionic liquids, and examines the challenges and opportunities relating to extending the use of DESs in lignocellulosic processing.

Author : Yizhak Marcus
Publisher : Springer
Page : 200 pages
File Size : 48,86 MB
Release : 2018-12-05
Category : Science
ISBN : 3030006085

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This is one of the first books fully dedicated to the rapidly advancing and expanding research area of deep eutectic solvents. Written by the internationally recognized expert in solution chemistry, it supplies full information regarding preparation of these new eco-friendly solvents, their properties and applications. The current and potential applications of deep eutectic solvents as organic reaction media, catalytic system, in biomass processing, nanotechnology and metal finishing industry, as well as for extraction and separation are extensively discussed.This highly informative and carefully presented book will appeal to practicing chemists (organic chemists, polymer chemists, biochemists) as well as chemical engineers and environmental scientists.

Author : Miguel M. Santos
Publisher : MDPI
Page : 154 pages
File Size : 25,43 MB
Release : 2021-09-01
Category : Science
ISBN : 3036500561

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Dear Colleagues, In recent years, functional coating technology has attracted increased attention due to its effective potential for improved engineered materials. Growing demand for new materials with synergistic properties pushed research toward a new field to obtain innovative and smart coatings with functional capabilities that greatly differ from the conventional ones. In such a context, the expression of “functional coatings” has acquired specific relevance. This Special Issue will assess cutting-edge developments in this research area for the improvement and growth of actual performance, industrial scale-up, and marketability of functional coatings. This Special Issue is useful for researchers who are approaching this application context to improve their knowledge, with the aim of providing valuable scientific support for new research paths concerning functional surface engineering design and tailoring. Prof. Luigi Calabrese, Prof. Edoardo Proverbio Guest Editors