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A Second-Order Nonlinear Optical Poly(Organophosphazene).

Author : Alexa A. Dembek
Publisher :
Page : 19 pages
File Size : 17,15 MB
Release : 1990
Category :
ISBN :

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A mixed substituent substituent polyphosphazenes with the structure (NPOCH2CF3) 64% (O(CH2CH2O)3-C6H4-CH=CH-C6H4-NO2) 36%(n) has been synthesized and the second-order nonlinear properties have been investigated. A second harmonic coefficient of d(33) = 5.5 pm/V was obtained. Reprints. (AW).

Polymers for Second-order Nonlinear Optics

Author : Geoffrey A. Lindsay
Publisher :
Page : 564 pages
File Size : 20,10 MB
Release : 1995
Category : Language Arts & Disciplines
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Presents the most recent developments in second-order nonlinear optical polymers. Covers the most important technologies necessary to achieve commercially viable devices based on special polymeric materials with second-order nonlinear optical properties. Discusses important molecular design considerations, how to process the polymers into films, the stability of the films, their optical properties, and prototype devices that can be made from these films.

Second Order Non-Linear Optical Polyphosphazenes. Proceedings of Symposium on Non-Linear Optics, ACS Meeting, Held in Boston, Massachusetts 1990

Author : Alexa A. Dembek
Publisher :
Page : 25 pages
File Size : 48,58 MB
Release : 1990
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In this contribution, we describe the synthesis and second-order optical properties of a series of mixed-substituent poly(organophosphazenes)that possess covalently attached donor-acceptor substituted, conjugated moieties. The general structure of the polymer is (NP(OCH2CF3)x(OR)(y))(n), where OR = -O(CH2O) (k)C6H4-CH=CH-C6H4NO2; where k = 1-3, and -OCH2CH2N(CH2CH3)C6H4-N=N-C6H4NO2, and x + y = 100%. The nonlinear optical properties of thin films of the polymers were investigated by using second harmonic generation, giving second-harmonic coefficients, d(33), in the range 4.1-34 pm/V. (AW).

Second-Order Nonlinear Optical Polymers: From Fundamentals to Applications

Author :
Publisher :
Page : 11 pages
File Size : 13,49 MB
Release : 1994
Category :
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Successful development of materials for photonic applications requires an understanding of the nonlinear optical process, chemistry and processing of materials, and technologies for device fabrications. We are able to successfully use different chemistries to develop several types of crosslinked and networked systems. Significant progress in improving material properties has been accomplished. Promising results have been observed in several materials developed. A prototype frequency doubling device has been prepared; second harmonic Cerenkov radiation emitting green and blue light have been observed. Relevant chemical modifications to fine-tune or enhance the desired properties will need to be iteratively performed to obtain optimized properties for practical applications. Polymeric materials, High speed EO modulation, Second-order nonlinearity, Optical losses.

Nonlinear Optical Properties of Polymers: Volume 109

Author : Alan J. Heeger
Publisher : Mrs Proceedings
Page : 416 pages
File Size : 30,57 MB
Release : 1988-04
Category : Science
ISBN :

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The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.