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Author : Anatolii Izrailevich Burshtein
Publisher :
Page : 300 pages
File Size : 46,21 MB
Release : 2005
Category : Gases
ISBN :
Author : A. I. Burshtein
Publisher : Cambridge University Press
Page : 312 pages
File Size : 25,8 MB
Release : 2005-07-14
Category : Science
ISBN : 9780521675581
Spectroscopic studies can reveal a wealth of information about the rotational and vibrational behavior of the constituent molecules of gases and liquids. This book reviews the fundamental concepts and models that underpin such studies. Throughout, discussion of the various quantum mechanical and semiclassical theories is interwoven with analysis of experimental results.
Author : A. Weber
Publisher : Springer Science & Business Media
Page : 327 pages
File Size : 50,54 MB
Release : 2012-12-06
Category : Science
ISBN : 3642812791
The Raman effect is a most useful tool for the study of molecular vibrations and molecular structure. Information about the structure and symmetry of molecules, as well as about their vibrational energies can be obtained to a reasonable degree of satisfaction from their infrared and Raman vibrational spectra. The body of knowl edqe of the vibrational infrared and Raman spectra of molecules is immense and is now so well organized and understood that it is found to be represented in any stan dard upper level undergraduate curriculum in chemistry. The rotational energies of a molecule and quantitative details about its structure can only be obtained through the techniques of microwave, and high-resolution infrared and Raman spectroscopy of low pressure gases and vapors. The results of such investigations are of interest . not only to the academic scientists, but also to scientists and engineers who are active in applied fields of chemistry and physics, as well as the atmospheric sciences. This book deals with basic investigations of the Raman scattering of light by gases, with some attention also being given to liquid substances. After a brief in troductory chapter that delineates the historical development of Raman spectroscopy of gases, high-resolution rotation-vibrational and pure rotational Raman spectros copy is described in Chapters 2 and 3. The all-important intensity parameter, the Raman scattering cross section, is treated in Chapter 4, while the broadening of Raman lines due to the effects of intermolecular forces is taken up in Chapter 5.
Author : A. I. Burshtein
Publisher : Cambridge University Press
Page : 310 pages
File Size : 16,83 MB
Release : 1994-07-21
Category : Science
ISBN : 0521454654
A review of the fundamental concepts and models which underpin the spectroscopic study of gases and liquids, first published in 1994.
Author : Karol Jackowski
Publisher : Royal Society of Chemistry
Page : 419 pages
File Size : 23,20 MB
Release : 2016-02-09
Category : Medical
ISBN : 1782623817
This book covers the recent NMR studies with the application of gaseous molecules. Among the comprehensively discussed aspects of the area it includes in particular: new multinuclear experiments that deliver spectral parameters of isolated molecules and provide the most accurate values of nuclear magnetic shielding, isotropic spin–spin coupling and relaxation times; advanced, precise and correct theoretical descriptions of spectral parameters of molecules as well as the application of gas-phase NMR measurements to chemical analysis and medicine. The progress of research in these fields is enormous and has rapidly changed our knowledge and understanding of molecular parameters in NMR spectroscopy. For example, accurate studies of the shielding for isolated molecules allow the exact determination of nuclear magnetic dipole moments, the calculated values of spectral parameters can be verified by precise gas-phase NMR measurements, and the application of hyperpolarized noble gases provides excellent MRI pictures of lungs. Aimed at graduates and researchers in spectroscopy, analytical chemistry and those researching the applications of NMR in medicine, this book presents the connections between sophisticated experiments, the theory of magnetic parameters and the exploration of new methods in practice.
Author : John M. Brown
Publisher : Cambridge University Press
Page : 1074 pages
File Size : 33,78 MB
Release : 2003-04-10
Category : Science
ISBN : 9780521530781
The definitive text on the rotational spectroscopy of diatomic molecules.
Author : Gordon M. Barrow
Publisher :
Page : 176 pages
File Size : 25,79 MB
Release : 1963
Category : Molecular spectra
ISBN :
This book deals with the methods of spectroscopy primarily in terms of the study of the properties of individual molecules.
Author : Dusan Papousek
Publisher : World Scientific
Page : 576 pages
File Size : 12,81 MB
Release : 1997-10-31
Category : Science
ISBN : 9814502456
The book reviews the results of vibration-rotational spectroscopy of molecules obtained recently by combining modern computational methods of quantum chemistry with the new techniques of high-resolution rotational and vibration-rotational spectroscopy. It shows for example that the tunneling vibration-rotational spectroscopy of the van der Waals complexes provides a new look at intermolecular forces while the high precision and sensitivity of the submillimeter-wave and Fourier transform microwave spectroscopy make it possible to study complex rotational spectra of molecules in excited vibrational states. New results of high level ab initio quantum chemical computations of vibrational and rotational energy levels and dipole moment functions of unusual molecules will be discussed together with the recent discovery of clustering of energy levels in asymmetric tops. Group theoretical analysis of floppy molecules, especially the tunneling effects in nonrigid molecules, will also be discussed.
Author : Walter G. Rothschild
Publisher : Wiley-Interscience
Page : 446 pages
File Size : 33,38 MB
Release : 1984-01-20
Category : Science
ISBN :
Good,No Highlights,No Markup,all pages are intact, Slight Shelfwear,may have the corners slightly dented, may have slight color changes/slightly damaged spine.
Author : James E. Wollrab
Publisher : Academic Press
Page : 485 pages
File Size : 34,76 MB
Release : 2013-10-22
Category : Science
ISBN : 148319485X
Physical Chemistry, A Series of Monographs: Rotational Spectra and Molecular Structure covers the energy levels and rotational transitions. This book is divided into nine chapters that evaluate the rigid asymmetric top molecules and the nuclear spin statistics for asymmetric tops. Some of the topics covered in the book are the asymmetric rotor functions; rotational transition intensities; classes of molecules; nuclear spin statistics for linear molecules and symmetric tops; and classical appearance of centrifugal and coriolis forces. Other chapters deal with the energy levels and effects of centrifugal distortion, as well as the internuclear distance and moments of inertia. The discussion then shifts to the coriolis coupling effects on rotational constants and the perturbation treatment of vibration-rotational Hamiltonian. The last chapter is devoted to the examination of origin of the quadrupole interaction. The book can provide useful information to chemists, physicists, electrical engineers, students, and researchers.