[PDF] Polymer Motion In Dense Systems eBook

Author : Dieter Richter
Publisher : Springer
Page : 0 pages
File Size : 40,1 MB
Release : 1988
Category : Science
ISBN : 9783642933806

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The nine review articles and roughly 30 contributed papers contained in this volume survey the present understanding of the molecular motion of polymers in concentrated solutions, melts and the amorphous state. Although the main emphasis is on results from neutron scattering experiments, about half of the contributions relate to complementary techniques such as light scattering and NMR. The book highlights three areas of active reseach that have received increasing attention in recent years. First, work on polymer relaxation near the glass transition and in glassy systems has shown that the application of different experimental techniques is indispensable due to the broad range of time scales over which these phenomena occur on a molecular level. Second, it is reported that the internal Brownian motion of long chain molecules and their diffusion in an entangled environment still does not have a generally accepted physical picture, although detailed insights into the microscopic motion have been obtained. Third, important progress has been made in unravelling the characteristics of phase separation of polymer blends, in which modifications to the ordinary laws of diffusion are of particular interest.

Author : Masao Doi
Publisher : Oxford University Press
Page : 420 pages
File Size : 49,13 MB
Release : 1988
Category : Science
ISBN : 9780198520337

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This book provides a comprehensive account of the modern theory for the dynamical properties of polymer solutions. The theory has undergone dramatic evolution over the last two decades due to the introduction of new methods and concepts that have extended the frontier of theory from dilute solutions in which polymers move independently to concentrated solutions where many polymers converge. Among the properties examined are viscoelasticity, diffusion, dynamic light scattering, and electric birefringence. Nonlinear viscoelasticity is discussed in detail on the basis of molecular dynamical models. The book bridges the gap between classical theory and new developments, creating a consistent picture of polymer solution dynamics over the entire concentration range.

Author : Y.-H. Lin
Publisher : World Scientific
Page : 441 pages
File Size : 40,73 MB
Release : 2011
Category : Science
ISBN : 9814313033

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This book covers in great detail the Rouse-segment-based molecular theories in polymer viscoelasticity ? the Rouse theory and the extended reptation theory (based on the framework of the Doi?Edwards theory) ? that have been shown to explain experimental results in a consistently quantitative way. The explanation for the 3.4 power law of viscosity, quantitative line-shape analyses of viscoelastic responses and agreements between different sorts of viscoelastic responses, the consistency between the viscoelasticity and diffusion results, the clarification of the onset of entangelement, the discovery of the number of entanglement strands per cubed entanglement distance being a universal constant and the basic mechanism of the glass transition-related thermorheological complexity are discussed or shown in great detail. The mystery behind the success of the Rouse-segment-based molecular theories over the entropic region of a viscoelastic response is revealed by the Monte Carlo simulations on the Fraenkel chains. Specifically, the simulation studies give a natural explanation for the coexistence of the energy-driven and entropy-driven modes in a viscoelastic response and provide a theoretical basis resolving the paradox that the experimentally determined sizes of Rouse and Kuhn segments are nearly the same. This book starts from a very fundamental level; each chapter is built upon the contents of the previous chapters. Thus, the readers may use the book as a textbook and eventually reach an advanced research level. This book is also a useful source of reference for physicists, chemists and material scientists.

Author : Yn-hwang Lin
Publisher : World Scientific
Page : 265 pages
File Size : 38,16 MB
Release : 2003-12-22
Category : Technology & Engineering
ISBN : 9814485802

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In this book, the studies of the Rouse, Doi-Edwards, and extended reptation theories are developed in a consistent manner from a basic level and discussed in detail. Viscoelastic properties of nearly monodisperse linear flexible polymers in both the entanglement and entanglement-free regions are analyzed quantitatively in terms of the molecular theories.

Author : Gert R. Strobl
Publisher : Springer Science & Business Media
Page : 525 pages
File Size : 21,65 MB
Release : 2007-08-02
Category : Science
ISBN : 3540684115

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The Physics of Polymers presents the elements of this important segment of material science, focusing on concepts above experimental techniques and theoretical methods. Written for graduate students of physics, material science and chemical engineering and for researchers working with polymers in academia and industry, the book introduces and discusses the basic phenomena which lead to the peculiar physical properties of polymeric systems. The revised and expanded Third Edition includes a new chapter dealing with conjugated polymers, explaining the physical basis of the characteristic electro-optic response, and the spectacular electrical conduction properties of conjugated polymers created by doping.

Author : S. I. Kuchanov
Publisher : VSP
Page : 210 pages
File Size : 23,39 MB
Release : 1992-01-01
Category : Science
ISBN : 9789067641456

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This book contains the plenary lectures from international experts, which were presented during the International Conference Polymer Networks, held in Moscow, April 1991. The book covers different areas of physics and chemistry of polymer networks, generated by the formation of chemical bonds. New theoretical and experimental results concerning the synthesis, structure and properties of such networks as recently obtained in scientific centres world-wide are extensively presented.

Author : G.M. Swallowe
Publisher : Springer Science & Business Media
Page : 313 pages
File Size : 45,79 MB
Release : 2013-04-17
Category : Science
ISBN : 9401592314

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This volume represents a continuation of the Polymer Science and Technology series edited by Dr. D. M. Brewis and Professor D. Briggs. The theme of the series is the production of a number of stand alone volumes on various areas of polymer science and technology. Each volume contains short articles by a variety of expert contributors outlining a particular topic and these articles are extensively cross referenced. References to related topics included in the volume are indicated by bold text in the articles, the bold text being the title of the relevant article. At the end of each article there is a list of bibliographic references where interested readers can obtain further detailed information on the subject of the article. This volume was produced at the invitation of Derek Brewis who asked me to edit a text which concentrated on the mechanical properties of polymers. There are already many excellent books on the mechanical properties of polymers, and a somewhat lesser number of volumes dealing with methods of carrying out mechanical tests on polymers. Some of these books are listed in Appendix 1. In this volume I have attempted to cover basic mechanical properties and test methods as well as the theory of polymer mechanical deformation and hope that the reader will find the approach useful.

Author : Abderrahim Boudenne
Publisher : John Wiley & Sons
Page : 1322 pages
File Size : 24,9 MB
Release : 2011-06-09
Category : Technology & Engineering
ISBN : 1119972884

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Multiphase polymeric systems include a wide range of materials such as composites, blends, alloys, gels, and interpenetrating polymer networks (IPNs). A one-stop reference on multiphase polymer systems, this book fully covers the preparation, properties, and applications of advanced multiphase systems from macro to nano scales. Edited by well-respected academics in the field of multiphase polymer systems, the book includes contributions from leading international experts. An essential resource for plastic and rubber technologists, filler specialists and researchers in fields studying thermal and electrical properties.