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New Frontiers in Catalysis, Parts A-C

Author : L. Guczi
Publisher : Elsevier
Page : 2955 pages
File Size : 49,68 MB
Release : 1993-04-20
Category : Technology & Engineering
ISBN : 0080887147

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These volumes comprise the proceedings of the major international meeting on catalysis which is held at 4 year intervals. The programme focussed on New Frontiers in Catalysis including nontraditional catalytic materials and environmental catalysis. The contributions cover a wide range of fundamental, applied, industrial and engineering aspects of catalysis. The extensive range of highly efficient industrial techniques for observing and characterizing catalytically important surfaces is evident. The programme covered the following sessions: Mechanism, theory, in situ methods; Catalytic reaction on atomically clean surfaces; Catalytic reaction on zeolites and related substances; New methods and principles for catalyst preparation; Hydrotreatment reactions (HDS, HDN); Characterization of catalysts, application of novel techniques; Selective oxidation; New catalytic aspects of heteropoly acids and related compounds; Reaction of hydrocarbons; Nontraditional catalytic materials; Fuel upgrading; Alkane activation; Acid-base catalysis; New selective catalytic reactons, fine chemicals; Environmental catalysis; Industrial catalysis, deactivation, reactivation; Synthesis from syngas; Electrocatalysis; Photocatalysis. The invited lectures and 433 papers included in these volumes present an update on all areas of catalysis and applications.

Characterization of Porous Solids III

Author : F. Rodríguez-Reinoso
Publisher : Elsevier
Page : 817 pages
File Size : 44,25 MB
Release : 1994-08-26
Category : Science
ISBN : 0080887376

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The objectives of the Third IUPAC Symposium on the Characterization of Porous Solids (COPS-III) were (1) to provide the opportunity for specialists to exchange ideas and new information on theoretical principles and methodology and (2) to generate proposals for the comparison and utilization of the many techniques now available for the characterization of porous solids. A successful outcome of the Symposium has been the final report of the IUPAC Subcommittee on Recommendations for the Characterization of Porous Solids, a summary of which is given in these proceedings. The edited papers included in the present volume have been selected from the 155 oral and poster presentations given at this symposium, which attracted 200 participants from 28 different countries. The following topics were discussed: 1. Simulation and modelling of pore structures and pore-filling mechanisms 2. Novel experimental techniques with particular reference to high-resolution techniques 3. Model pore structures and reference materials 4. Porous materials of technological importance. The wide range of materials and techniques described provide a useful and comprehensive reference source for academic and industrial scientists and technologists.

Catalysis: An Integrated Approach

Author : B.A. Averill
Publisher : Elsevier
Page : 603 pages
File Size : 47,31 MB
Release : 1999-09-07
Category : Technology & Engineering
ISBN : 0080528643

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This book concentrates on industrially relevant reactions which are catalyzed by heterogeneous and homogeneous catalysts. Homogeneous catalysis by metal complexes is treated jointly with heterogeneous catalysis using metallic and non-metallic solids. In both areas the high degree of sophistication of spectroscopic techniques and theoretical modelling has led to an enormous increase in our understanding at the molecular level. This holds for the kinetics of the reactions and the reactivities of the catalysts, as well as for the syntheses of the catalytic materials. The development of catalysis science since the first edition of this book has necessitated a thorough revision, including special chapters on biocatalysis, catalyst characterization and adsorption methods. The multidisciplinary nature of catalysis is reflected in the choice of a novel combination of basic disciplines which will be refreshing and inspiring to readers.

Catalytic Polymerization of Cycloolefins

Author : V. Dragutan
Publisher : Elsevier
Page : 1293 pages
File Size : 44,46 MB
Release : 2000-06-26
Category : Technology & Engineering
ISBN : 0080528627

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This book covers the most important topics concerning cationic Ziegler-Natta and ring-opening metathesis polymerization of cycloolefins. The work describes the major pathways that cycloolefins can follow under the action of specific catalytic systems, essentially vinyl and ring-opening polymerization, both reaction types allowing the manufacture of distinct products with wide applicability in modern technologies. The comprehensive data available on this subject are logically and systematically selected and reviewed throughout 18 chapters, according to the basic catalytic processes involved, types of monomers and catalysts employed, reaction conditions and application fields. The modern trends in design of chiral metallocene catalysts, well-defined living metathesis catalysts, catalysts tolerant toward functionalities and water systems are highlighted. The book discusses in detail the relevant aspects of these processes including reaction thermodynamics, kinetics, mechanisms and stereochemistry and correlates the structure of produced polymers with their chemical and physical-mechanical properties. Related important topics include Ziegler-Natta polymerization of olefins and dienes, atom transfer radical polymerization of vinyl compounds, metathesis of olefins and acetylenes, acyclic diene metathesis reaction, carbonyl olefination reaction, metathesis polymerization of acetylenes, metathesis degradation of polymers and ring-opening polymerization of heterocycles. Special emphasis is laid upon the manufacture of commerical products, new polymers and copolymers of potential interest for industry and design and synthesis of speciality polymers with particular structures and architectures and desired properties. The book critically evaluates the most recent achievements reported in this field and outlines the modern trends on the research and application of the catalytic processes for cycloolefin polymerization. For the first time, comprehensive information about the published data on the subject up to now is provided for both academic and industrial researchers working in the areas of polymer chemistry, organic and organometallic chemistry, surface science and catalysis, petrochemistry and chemical engineering. This stimulating book offers an enlightening introduction and a quick documentation on the subject as well as a solid background in this field. Moreover, the work offers a wealth of useful information for specialists applying polymers in various scientific and industrial areas.

Experiments in Catalytic Reaction Engineering

Author : J.M. Berty
Publisher : Elsevier
Page : 289 pages
File Size : 45,81 MB
Release : 1999-08-11
Category : Technology & Engineering
ISBN : 0080531423

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The science of catalytic reaction engineering studies the catalyst and the catalytic process in the laboratory in order to predict how they will perform in production-scale reactors. Surprises are to be avoided in the scaleup of industrial processes. The laboratory results must account for flow, heat and mass transfer influences on reaction rate to be useful for scaleup. Calculated performance based on these results must also be useful to maximization of profit and safety and minimization of pollution. To this end, information on products as well as byproducts and heat produced must be generated. If a sufficiently large database of knowledge is produced, optimization studies will be possible later if economic conditions change. The field of reaction engineering required new tools. For kinetic and catalyst testing, the most successful of these tools was the internal recycle reactor. Studies in recycle reactors can be made under well-defined conditions of flow and associated transfer processes, and close to commercial operation. The recycle reactor eliminates or minimizes the effect of transfer process, and allows the remaining ones to be known. Features of this book: • Provides insight into a field that is neither well understood nor properly appreciated. • Gives a deeper understanding of reaction engineering practice. • Helps avoid frustration and disappointment in industrial research. This book is short and clear enough to assist all members of the R&D and Engineering team, whether reaction engineers, or specialists in other fields. This is critical in this new age of computation and communication, when team members must each know at least something of their colleagues' fields. Additionally, many scientists in more exploratory or fundamental fields can use recycle reactors to study basic phenomena free of transfer interactions.

Catalysis by Metals and Alloys

Author : V. Ponec
Publisher : Elsevier
Page : 745 pages
File Size : 16,24 MB
Release : 1995-08-29
Category : Science
ISBN : 0080528651

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Catalysis by Metals and Alloys

Preparation of Catalysts VI

Author : G. Poncelet
Publisher : Elsevier
Page : 1205 pages
File Size : 43,52 MB
Release : 1995-03-24
Category : Science
ISBN : 0080544665

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The organizers of this Sixth Symposium maintained their initial objectives, namely to gather experts from both industries and universities to discuss the scientific problems involved in the preparation of heterogeneous catalysts, and to encourage as much as possible the presentation of research work on catalysts of real industrial significance. Another highlight of these symposia is to reserve a substantial part of the program to new developments in catalyst preparation, new preparation methods and new catalytic systems. The fact that chemical reactions which were hardly conceivable some years ago have become possible today through the development of appropriate catalytic systems proves that catalysis is in constant progress. The papers in this volume deal with preparation of new catalysts and supports, catalyst preparation via sol-gel methods, supported catalysts and synthesis of nanometer size catalysts.

Acid-Base Catalysis II

Author : H. Hattori
Publisher : Elsevier
Page : 593 pages
File Size : 26,27 MB
Release : 1994-11-01
Category : Technology & Engineering
ISBN : 008088752X

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Solid acid catalysts are already being used in various processes in petroleum refining and are presently being studied intensively in both academic and applied fields for usage in a variety of reactions. Solid base catalysts are also gaining increasing recognition as potential catalysts. Both acidic and basic catalysts are promising not only with respect to acid and base-catalyzed reactions but also in materials sciences, such as the production of adsorbents, sensors, ceramics, etc. The present volume presents the text of 21 invited oral presentations and 58 poster presentations. The material covers a wide range of aspects on acid-base catalysis, from quantum chemistry to industrialized processes.