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Author : Michael D. Max Publisher : Springer Science & Business Media Page : 362 pages File Size : 19,42 MB Release : 2006-07-09 Category : Science ISBN : 1402039727
This book is a companion to “Natural Gas Hydrate in Oceanic and Permafrost Environments” (Max, 2000, 2003), which is the first book on gas hydrate in this series. Although other gases can naturally form clathrate hydrates (referred to after as ‘hydrate’), we are concerned here only with hydrocarbon gases that form hydrates. The most important of these natural gases is methane. Whereas the first book is a general introduction to the subject of natural gas hydrate, this book focuses on the geology and geochemical controls of gas hydrate development and on gas extraction from naturally occurring hydrocarbon hydrates. This is the first broad treatment of gas hydrate as a natural resource within an economic geological framework. This book is written mainly to stand alone for brevity and to minimize duplication. Information in Max (2000; 2003) should also be consulted for completeness. Hydrate is a type of clathrate (Sloan, 1998) that is formed from a cage structure of water molecules in which gas molecules occupying void sites within the cages stabilize the structure through van der Waals or hydrogen bonding.
“Natural Gas Hydrates: Experimental Techniques and Their Applications” attempts to broadly integrate the most recent knowledge in the fields of hydrate experimental techniques in the laboratory. The book examines various experimental techniques in order to provide useful parameters for gas hydrate exploration and exploitation. It provides experimental techniques for gas hydrates, including the detection techniques, the thermo-physical properties, permeability and mechanical properties, geochemical abnormalities, stability and dissociation kinetics, exploitation conditions, as well as modern measurement technologies etc. This book will be of interest to experimental scientists who engage in gas hydrate experiments in the laboratory, and is also intended as a reference work for students concerned with gas hydrate research. Yuguang Ye is a distinguished professor of Experimental Geology at Qingdao Institute of Marine Geology, China Geological Survey, China. Professor Changling Liu works at the Qingdao Institute of Marine Geology, China Geological Survey, China.
1. THE BEGINNINGS OF HYDRATE RESEARCH Until very recently, our understanding of hydrate in the natural environment and its impact on seafloor stability, its importance as a sequester of methane, and its potential as an important mechanism in the Earth's climate change system, was masked by our lack of appreciation of the vastness of the hydrate resource. Only a few publications on naturally occurring hydrate existed prior to 1975. The first published reference to oceanic gas hydrate (Bryan and Markl, 1966) and the first publication in the scientific literature (Stoll, et a1., 1971) show how recently it has been since the topic of naturally occurring hydrate has been raised. Recently, however, the number of hydrate publications has increased substantially, reflecting increased research into hydrate topics and the initiation of funding to support the researchers. Awareness of the existence of naturally occurring gas hydrate now has spread beyond the few scientific enthusiasts who pursued knowledge about the elusive hydrate because of simple interest and lurking suspicions that hydrate would prove to be an important topic. The first national conference on gas hydrate in the U.S. was held as recently as April, 1991 at the U.S. National Center of the U.s. Geological Survey in Reston Virginia (Max et al., 1991). The meeting was co-hosted by the U.s. Geological Survey, the Naval Research Laboratory, and the U.S.
The book is an up-to-date basic reference for natural gas hydrate (NGH) in the Arctic Ocean. Geographical, geological, environmental, energy, new technology, and regulatory matters are discussed. The book should be of interest to general readers and scientists and students as well as industry and government agencies concerned with energy and ocean management. NGH is a solid crystalline material that compresses gas by about a factor of about 164 during crystallization from natural gas (mainly methane) - rich pore waters over time. NGH displaces water and may form large concentrations in sediment pore space. Its formation introduces changes in the geotechnical character of host sediment that allows it to be distinguished by seismic and electric exploration methods. The chemical reaction that forms NGH from gas and water molecules is highly reversible, which allows controlled conversion of the NGH to its constituent gas and water. This can be achieved rapidly by one of a number of processes including heating, depressurization, inhibitor injection, dissolution, and molecular replacement. The produced gas has the potential to make NGH a valuable unconventional natural gas resource, and perhaps the largest on earth. Estimates for NGH distribution, concentration, economic targets, and volumes in the Arctic Ocean have been carried out by restricting the economic target to deepwater turbidite sands, which are also sediment hosts for more deeply buried conventional hydrocarbon deposits. Resource base estimates are based on NGH petroleum system analysis approach using industry-standard parameters along with analogs from three relatively well known examples (Nankai-Japan, Gulf of Mexico-United States, and Arctic permafrost hydrate). Drilling data has substantiated new geotechnical-level seismic analysis techniques for estimating not just the presence of NGH but prospect volumes. In addition to a volumetric estimate for NGH having economic potential, a sedimentary depositional model is proposed to aid exploration in the five different regions around the deep central Arctic Ocean basin. Related topics are also discussed. Transport and logistics for NGH may also be applicable for stranded conventional gas and oil deposits. Arising from a discussion of new technology and methodologies that could be applied to developing NGH, suggestions are made for the lowering of exploration and capital expenses that could make NGH competitive on a produced cost basis. The basis for the extraordinarily low environmental risk for exploration and production of NGH is discussed, especially with respect to the environmentally fragile Arctic region. It is suggested that because of the low environmental risk, special regulations could be written that would provide a framework for very low cost and safe development.
“Natural Gas Hydrates: Experimental Techniques and Their Applications” attempts to broadly integrate the most recent knowledge in the fields of hydrate experimental techniques in the laboratory. The book examines various experimental techniques in order to provide useful parameters for gas hydrate exploration and exploitation. It provides experimental techniques for gas hydrates, including the detection techniques, the thermo-physical properties, permeability and mechanical properties, geochemical abnormalities, stability and dissociation kinetics, exploitation conditions, as well as modern measurement technologies etc. This book will be of interest to experimental scientists who engage in gas hydrate experiments in the laboratory, and is also intended as a reference work for students concerned with gas hydrate research. Yuguang Ye is a distinguished professor of Experimental Geology at Qingdao Institute of Marine Geology, China Geological Survey, China. Professor Changling Liu works at the Qingdao Institute of Marine Geology, China Geological Survey, China.
There is much interest in gas hydrates in relation to their potential role as an important driver for climate change and as a major new energy source; however, many questions remain, not least the size of the global hydrate budget. Much of the current uncertainty centres on how hydrates are physically stored in sediments at a range of scales. This volume details advances in our understanding of sediment-hosted hydrates, and contains papers covering a range of studies of real and artificial sediments containing both methane hydrates and CO2 hydrates. The papers include an examination of the techniques used to locate, sample and characterize hydrates from natural, methane-rich systems, so as to understand them better. Other contributions consider the nature and stability of synthetic hydrates formed in the laboratory, which in turn improve our ability to make accurate predictive models.
Gas hydrates are ice-like crystalline substances that form a rigid cage of water molecules and entrap hydrocarbon and non-hydrocarbon gas by hydrogen bonding. Natural gas hydrate is primarily composed of water and methane. These are solid, crystalline, ice-like substances found in permafrost areas and deepwater basins around the world. They naturally occur in the pore space of marine sediments, where appropriate high pressure and low temperature conditions exist in an adequate supply of gas (mainly methane). Gas hydrates are considered as a potential non conventional energy resource. Methane hydrates are also recognized as, an influence on offshore platform stability, a major factor in climate change contributing to global warming and a significant contribution to the ocean carbon cycle. The proposed book treats various geophysical techniques in order to quantify the gas hydrate reserves and their impact on environment. The primary goal of this book is to provide the state of art for gas hydrate exploration. The target audiences for this book are non-specialist from different branches of science, graduate students and researchers.