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Catalytic Carbonylation Reactions

Author : Matthias Beller
Publisher : Springer Science & Business Media
Page : 289 pages
File Size : 20,55 MB
Release : 2006-09-14
Category : Science
ISBN : 354033002X

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Carbonylation reactions are of major importance in both organic and industrial chemistry. Due to the availability, price and reactivity pattern, carbon monoxide is becoming a more and more important building block for fine and bulk chemicals. The major reaction types of carbon monoxide are comprehensively discussed by leading experts from academia and industry. The authors highlight important carbonylation reactions such as hydroformylation, alkoxy-carbonylations, co/olefin-copolymerization, Pauson-Khand reactions and others. They illustrate applications in organic synthesis and give industrial examples. This volume is designed to provide graduate students and researchers with essential information on the use of carbon monoxide in organic synthesis. Therefore, the reader will get a balanced view of this developing and complex subject.

Carbonylation

Author : H.M. Colquhoun
Publisher : Springer Science & Business Media
Page : 295 pages
File Size : 29,91 MB
Release : 2013-06-29
Category : Science
ISBN : 1475795769

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Since the publication of our earlier book on transition metal mediated organic synthesis, * there has been a widespread increase of interest in this topic, and transition metal based methodology has become firmly established in many areas of organic chemistry. The direct, catalytic formation of organic carbonyl compounds using carbon monoxide as the source of the carbonyl group has seen exceptional progress, and this carbonylation chemistry is being used increasingly in research and on a larger scale for fine chemicals production. In view of these developments, there is a need for a modem, practi cally oriented book dealing with transition metal based carbonylation chemistry. The present monograph should help fulfill this need, since it is intended specifically to foster the adoption of catalytic carbonylation as a general tool in synthetic organic chemistry. It deals exclusively with reactions involving the interconversion of carbon monoxide and organic carbonyl compounds, and although the majority of the reactions discussed involve catalytic formation of carbonyl compounds, potentially valuable syntheses requiring stoichiometric quantities of transition metal are also included. In addition, a chapter is devoted to the remarkably useful reverse transformation (decarbonylation), in which an organic carbonyl group is eliminated in the form of carbon monoxide.

Aqueous Organometallic Catalysis

Author : Ferenc Joó
Publisher : Springer Science & Business Media
Page : 307 pages
File Size : 11,97 MB
Release : 2006-04-11
Category : Science
ISBN : 0306475103

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Over the past 20 years aqueous organometallic catalysis has found applications in small- scale organic synthesis in the laboratory, as well as in the industrial production of chemicals with a combined output close to one million tons per year. Aqueous/organic two-phase reactions allow easy product-catalyst separation and full catalyst recovery which mean clear benefits not only in economic but also in environmental and green chemistry contexts. Instead of putting together a series of expert reviews of specialized fields, this book attempts to give a comprehensive yet comprehensible description of the various catalytic transformations in aqueous systems as seen by an author who has been working on aqueous organometallic catalysis since its origin. Emphasis is put on the discussion of differences between related non-aqueous and aqueous processes due to the presence of water. The book will be of interest to experts and students working in catalysis, inorganic chemistry or organic synthesis, and may serve as a basis for advanced courses.

Comprehensive Organic Reactions in Aqueous Media

Author : Chao-Jun Li
Publisher : John Wiley & Sons
Page : 435 pages
File Size : 48,91 MB
Release : 2007-06-04
Category : Science
ISBN : 0470131438

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An extensive update of the classic reference on organic reactions in water Published almost a decade ago, the first edition has served as the guide for research in this burgeoning field. Due to the cost, safety, efficiency, and environmental friendliness of water as a solvent, there are many new applications in industry and academic laboratories. More than forty percent of this extensively updated second edition covers new reactions. For ease of reference, it is organized by functional groups. A core reference, Comprehensive Organic Reactions in Aqueous Media, Second Edition: * Provides the most comprehensive coverage of aqueous organicreactions available * Covers the basic principles and theory and progresses to applications * Includes alkanes, alkenes, aromatics, electrophilic substitutions, carbonyls, alpha, beta-unsaturated carbonyls, carbon-nitrogen bonds, organic halides, pericyclic reactions, photochemical reactions, click chemistry, and multi-step syntheses? * Provides examples of applications in industry This is the premier reference for chemists and chemical engineers in industry or research, as well as for students in advanced-level courses.

Carbon Monoxide in Organic Synthesis

Author : Jürgen Falbe
Publisher : Springer Science & Business Media
Page : 228 pages
File Size : 15,16 MB
Release : 2013-03-14
Category : Science
ISBN : 3642858570

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This book reviews some important reactions of carbon monoxide in organic chemistry: hydroformylation, metal carbonyl- and acid catalyzed carbonylation and ring closure reactions with carbon monoxide. It is not merely a translation of the German edition which appeared in 1967 but the text has been completely revised. This was necessary because this chemistry is rapidly developing in research as well as in technical application, which is underlined by the increase of production of e. g. oxo chemicals from about 1.4 million tons in 1967 to 2.7 million tons in 1969, nearly a doubling within 2 years. Quite a number of new research results were published during the last two years, and these additional references have been cited in the English edition. Most of the new papers cited deal with hydroformylation reactions: however, a number of the papers reviewed also report important new aspects in carboxylation and ring closure reactions. The author is indebted to a number of colleagues who helped to collect these new data and have given him valuable hints and would like to thank Miss 1. Forster, Dr. B. Cornils, Dr. D. Hahn, Dr. P. Schneller, Dr. H. Tummes, and Dr. J. Weber for their cooperation, and to Prof. Dr. F. Piacenti (University of Pisa, Italy) for discussions on reaction mecha nisms. The author is especially grateful to Dr. Charles R. Adams of the Shell Development Company, Emeryville, California, for his cooperation in translating the German text.

Studies in Catalytic Carbonylation Reactions

Author : Pawan Tambade
Publisher : LAP Lambert Academic Publishing
Page : 236 pages
File Size : 15,91 MB
Release : 2014-11-01
Category :
ISBN : 9783659631184

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This book covers various aspects of the catalytic carbonylation reactions. It includes both the review on the modern catalytic methods for carbonylation of aryl halides and also the results of the studies done by the authors. The present work is a prolific attempt to demonstrate our contribution to the area of carbonylation reactions using environmentally acceptable protocols. The main theme of research work was the development of novel and greener catalytic method for the wider substrate configuration. High priority for the replacement of phospine based protocols. Use of structurally well defined o-containing complex, ligand-free reactions in water and heterogeneous Pd catalyst was the major aspect of the present work.

Modern Carbonylation Methods

Author : László Kollár
Publisher : John Wiley & Sons
Page : 383 pages
File Size : 42,68 MB
Release : 2008-06-25
Category : Science
ISBN : 3527621555

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Comprehensively covering modern carbonylation chemistry, this book is an indispensable companion for all synthetic chemists working in industry and academia. This monograph contains everything there is to know from recent advances in the investigation of carbonylation catalysts, via coordination chemistry to the synthetic application of transition metal catalyzed carbonylations.

Homogeneous Carbonylation and Hydroformylation Reactions

Author : Mohammad Reza Rahimpour
Publisher : Elsevier
Page : 260 pages
File Size : 13,37 MB
Release : 2024-08-30
Category : Technology & Engineering
ISBN : 0443155615

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Homogeneous Carbonylation and Hydroformylation Reactions with Homogeneous Catalysts and Process Development, a volume is in the Advances in Catalysis series, is split into two sections. The first covers the homogeneous carbonylation of various chemicals, such as methanol, methyl acetate, esters and ethers. In addition, some common carbonylation homogeneous processes such as water-gas shift and Fischer–Tropsch reactions are included. The second part describes hydroformylation processes like cobalt and rhodium based reactions. Both parts cover the design of catalytic reactors, industrial applications, economic assessment and environmental impacts providing detailed discussions of the subject from both a chemistry and engineering perspective. Includes fundamentals, reactor design, and process description of carbonylation and hydroformylation homogeneous reactions Describes various carbonylation and hydroformylation homogeneous reactions Explains carbonylation and hydroformylation economic and environmental challenges

Organic Reactions in Aqueous Media

Author : Chao-Jun Li
Publisher : Wiley-Interscience
Page : 224 pages
File Size : 42,82 MB
Release : 1997-08-19
Category : Science
ISBN :

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From cost and safety to synthetic efficiency and environmental friendliness, water has many potential advantages as a solvent for organic reactions. This book examines different aspects of organic reactions in water, enabling readers to gain an essential understanding of current thinking on a range of reaction types and techniques. Beginning with basic theory and progressing to synthetic applications, Organic Reactions in Aqueous Media is an ideal platform for both advanced-level study and practical research. It covers these key areas: * Fundamental properties of water * Pericyclic reactions-including Diels-Alder reactions * Nucleophilic additions and substitutions * Metal mediated reactions * Transition metal catalyzed reactions * Oxidations and reductions * Industrial applications